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a) \(m_{CuO}=\dfrac{20.40}{100}=8\left(g\right)\) => \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(m_{Fe_2O_3}=20-8=12\left(g\right)\) => \(n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1--->0,1------>0,1
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,075--->0,225----->0,15
=> mCu = 0,1.64 = 6,4 (g)
=> mFe = 0,15.56 = 8,4 (g)
b) \(V_{H_2}=\left(0,1+0,225\right).22,4=7,28\left(l\right)\)
a) \(n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{3}{14}\)---------------------->\(\dfrac{3}{14}\)
\(\Rightarrow V_{H_2}=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
b) \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
PTHH: \(ZnO+H_2\xrightarrow[]{t^o}Zn+H_2O\)
Xét tỉ lệ: \(0,1< \dfrac{3}{14}\Rightarrow H_2\) dư
Theo PT: \(n_{Zn}=n_{ZnO}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(1mol\) \(1mol\)
\(\dfrac{3}{14}mol\) \(\dfrac{3}{14}mol\)
\(a)n_{Fe}=\dfrac{m}{M}=\dfrac{12}{56}\approx0,21=\dfrac{3}{14}\left(mol\right)\)
\(V_{H_2}=n.22,4=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
\(b)n_{ZnO}=\dfrac{m}{M}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(ZnO+H_2\rightarrow Zn+H_2O\)
\(1mol\) \(1mol\) \(1mol\)
\(0,1mol\) \(0,1mol\) \(0,1mol\)
\(\text{Ta thấy }H_2\text{ dư,ZnO phản ứng hết.Bài toán tính theo ZnO}\)
\(m_{Zn}=n.M=0,1.65=6,5\left(g\right)\)
Sửa đề: 1,2 (l) → 1,12 (l)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{CuO}=n_{H_2}=0,05\left(mol\right)\)
a, \(m_{CuO}=0,05.80=4\left(g\right)\)
b, \(m_{Cu}=0,05.64=3,2\left(g\right)\)
c, PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,025\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,025.22,4=0,56\left(l\right)\)
a, nZn = 26/65 = 0,4 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
nZn = nH2 = 0,4 (mol)
VH2 = 0,4 . 22,4 = 8,96 (l)
b, nFe2O3 = 16/160 = 0,1 (mol)
PTHH: Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
LTL: 0,1 < 0,4/3 => H2 dư
nFe = 0,1 . 3 = 0,3 (mol)
mFe = 0,3 . 56 = 16,8 (g)
a) \(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,4--------------------->0,4
=> VH2 = 0,4.22,4 = 8,96 (l)
b)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{3}\) => Fe2O3 hết, H2 dư
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1---------------->0,2
=> mFe = 0,2.56 = 11,2 (g)
nFe2O3 = 16,8/56 = 0,3 (mol)
PTHH: Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
MOL: 0,15 <--- 0,45 <--- 0,3
VH2 = 0,45 . 22,4 = 10,08 (l)
mFe2O3 = 0,45 . 160 = 72 (g)
a ) Fe2O3 + 3H2 ---> 2Fe + 3H2O
nFe = 16,8 :56 =0,3
Fe2O3 + 3H2--> 2Fe +3H2O
0,15<------0,45<---- 0,3
VH2 = 0,45.22,4=10,08(l)
mFe2O3 = 0,15.160 =24(g)
\(n_{ZnO}=\dfrac{m}{M}=\dfrac{16,2}{65+16}=0,2\left(mol\right)\)
a) \(PTHH:Zn+H_2O\rightarrow ZnO+H_2\)
1 1 1 1
0,2 0,2 0,2 0,2
b) \(V_{H_2}=n.24,79=0,2.24,79=4,958\left(l\right)\)
c) \(m_{Zn}=n.M=0,2.65=13\left(g\right).\)
\(Fe_3O_4+4CO\rightarrow\left(t^o\right)3Fe+4CO_2\)
0,3 0,225 ( mol )
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,15 0,15 ( mol )
\(V_{CO}=n.22,4=0,2.22,4=6,72l\)
\(V_{H_2}=n.22,4=0,15.22,4=3,36l\)
\(m_{Fe}=n.M=0,225.56=12,6g\)
\(m_{Cu}=n.M=0,15.64=9,6g\)
