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a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(2mol\) \(6mol\) \(2mol\) \(3mol\)
\(0,27\) \(x\) \(y\) \(z\)
b) ta có: \(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{7,3}{27}=0,27\left(mol\right)\)
theo PT: \(n_{Al}=n_{AlCl_3}=0,27\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=n_{AlCl_3}.M_{AlCl_3}=0,27.133,5=36,045\left(g\right)\)
c) ta có: \(n_{H_2}=\dfrac{m_{H_2}}{M_{H_2}}=\) \(\dfrac{0,27.3}{2}=0,405\left(mol\right)\)
\(\Rightarrow V_{H_2\left(đktc\right)}=n_{H_2}.22,4=0,405.22,4=9,072\left(l\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,4
0,1 0,2
0 0,2 0,1 0,1
\(a,V_{H_2}=0,1.22,4=2,24\left(l\right)\\ b,m_{dd}=6,5+0,4.36,5+50-0,1.2=70,9\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,1.136}{70,9}.100\%=19,18\%\)
a) pt: 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
nAl = \(\dfrac{5,4}{27}=0,2mol\)
Theo pt: nH2 = \(\dfrac{3}{2}nAl=0,3mol\)
=> VH2 = 0,3.22,4 = 6,72lit
c) nHCl = 3nAl = 0,6mol
=> mHCl = 21,9g
=> C% = \(\dfrac{21,9}{200}.100\%=10,95\%\)
d) Bảo toàn khối lượng
mdung dich muối = mAl + mHCl - mH2
= 5,4 + 200 - 0,3.2 = 204,8g
Theo pt:nAlCl3 = nAl = 0,2mol
=> mAlCl3 = 0,2.133,5 = 26,7g
=> C%dd muối = \(\dfrac{26,7}{204,8}.100\%=13,03\%\)
e) H2 + CuO \(\xrightarrow[]{t^o}\) Cu + H2O
nCu = nH2 = 0,3mol
=> mCu = 0,3.64 = 19,2g
\(a) 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ b) n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ n_{Al} = \dfrac{2}{3}n_{H_2} = 0,2(mol)\\ m_{Al} = 0,2.27 = 5,4(gam)\\ c) n_{HCl\ pư} = 2n_{H_2} = 0,6(mol)\\ n_{HCl\ đã\ dùng} = \dfrac{0,6}{80\%} = 0,75(mol)\\ m_{dd\ HCl} = \dfrac{0,75.36,5}{54,75\%} = 50(gam)\)
`a)PTHH:`
`2Al + 6HCl -> 2AlCl_3 + 3H_2`
`0,2` `0,6` `0,3` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`b)V_[H_2]=0,3.22,4=6,72(l)`
`c)m_[dd HCl]=[0,6.36,5]/10 . 100 =219(g)`
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
a) \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
Theo PTHH: \(n_{AlCl_3}=n_{Al}=\dfrac{2}{3}.n_{H_2}=\dfrac{2}{3}.0,6=0,4\left(mol\right)\)
=> mAl = 0,4.27 = 10,8 (g)
b) \(m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\)
Bài 1 :
a. \(n_{Al}=\dfrac{2.7}{27}=0,1\left(mol\right)\)
PTHH : 2Al + 6HCl -> 2AlCl3 + 3H2
0,1 0,3 0,15
b. \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c. \(m_{HCl}=0,3.36,5=10,95\left(g\right)\)
Bài 2 :
a. \(n_{Na}=\dfrac{2.3}{23}=0,1\left(mol\right)\)
PTHH : 2Na + 2H2O -> 2NaOH + H2
0,1 0,1 0,05
b. \(V_{H_2}=0,05.22,4=1,12\left(l\right)\)
c. \(m_{NaOH}=0,1.40=4\left(g\right)\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); nHCl = 0,5.2 = 1 (mol)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,1->0,3---->0,1---->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)