Cho 4,8 gam Mg tác dụng hết với dung dịch CHCOOH 12%.
a) Viết phương trình hóa học xảy ra.
b). Tính thể tích hidro thu được (dktc)
c) Tính khối lượng muối thu được sau phản ứng
d). Tính khối lượng dung dịch CH3COOH 12% đã dùng.
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\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ a,PTHH:Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ b,n_{H_2}=n_{\left(CH_3COO\right)_2Zn}=n_{Zn}=0,3\left(mol\right);n_{CH_3COOH}=2.0,3=0,6\left(mol\right)\\ b,V_{H_2\left(đkc\right)}=24,79.0,3=7,437\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Zn}=0,3.183=54,9\left(g\right)\\ d,C_2H_5OH+CH_3COOH\rightarrow CH_3COOC_2H_5+H_2O\\ n_{Este\left(LT\right)}=n_{CH_3COOH}=0,6\left(mol\right)\\ n_{este\left(TT\right)}=80\%.0,6=0,48\left(mol\right)\\ m=m_{este\left(TT\right)}=88.0,48=42,24\left(g\right)\)
\(n_{BaCO_3}=\dfrac{19,7}{197}=0,1\left(mol\right)\\ a,PTHH:BaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ba+CO_2+H_2O\\ n_{CO_2}=n_{\left(CH_3COO\right)_2Ba}=n_{BaCO_3}=0,1\left(mol\right)\\ b,V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Ba}=255.0,1=25,5\left(g\right)\\ d,C_2H_5OH+O_2\rightarrow\left(men.giấm\right)CH_3COOH+H_2O\\ n_{CH_3COOH}=0,1.2=0,2\left(mol\right);n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,2\left(mol\right)\\ n_{C_2H_5OH\left(TT\right)}=0,2.75\%=0,15\left(mol\right)\\ m_{C_2H_5OH\left(TT\right)}=0,15.46=6,9\left(g\right)\)
\(n_{CaCO_3}=\dfrac{20}{100}=0,2\left(mol\right)\\ a,PTHH:CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ b,n_{CO_2}=n_{\left(CH_3COO\right)_2Ca}=n_{CaCO_3}=0,2\left(mol\right)\\ b,V_{CO_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Ca}=0,2.158=31,6\left(g\right)\\ d,C_4H_{10}+\dfrac{5}{2}O_2\rightarrow2CH_3COOH+H_2O\\ n_{C_4H_{10}\left(LT\right)}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ n_{C_4H_{10}\left(TT\right)}=0,2:50\%=0,4\left(mol\right)\\ m_{C_4H_{10}\left(tt\right)}=58.0,4=23,2\left(g\right)\)
a) PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)=n_{MgCl_2}\)
\(\Rightarrow m_{MgCl_2}=0,15\cdot95=14,25\left(g\right)\)
c) Theo PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(p.ứ\right)}=0,3\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl\left(p.ứ\right)}=0,3\cdot36,5=10,95\left(g\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Mg}+m_{ddHCl}-m_{H_2}=53,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=50\left(g\right)\) \(\Rightarrow C\%_{HCl\left(p.ứ\right)}=\dfrac{10,95}{50}\cdot100\%=21,9\%\)
\(Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2\)
b)
\(n_{H_2}= \dfrac{2,24}{22,4}= 0,1 mol\)
\(\)Theo PTHH:
\(n_{ZnSO_4}= n_{H_2}= 0,1 mol\)
\(m_{ZnSO_4}= 0,1 . 161=16,1g\)
c)
Theo PTHH:
\(n_{H_2SO_4}= n_{H_2}= 0,1 mol\)
\(\Rightarrow m_{H_2SO_4}= 0,1 . 98= 9,8g\)
\(\Rightarrow m_{dd H_2SO_4}= \dfrac{9,8 . 100}{20}=49g\)
Sửa đề : 11.2 g sắt
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.2....0.2.................0.2\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)
a) \(n_{H_2}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,1------------------------------->0,1
b) VH2 = 0,1.22,4 = 2,24 (l)
c) \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,15 > 0,1 => CuO dư
Theo pthh: nCu = nH2 = 0,1 (mol)
=> mCu = 0,1.64 = 6,4 (g)
nMg = 3,6 : 24 = 0,15 (mol)
pthh : Mg + 2HCl --> MgCl2 + H2
0,15-----------> 0,15 --->0,15 (mol)
mMgCl2 = 0,15 . 95 = 14,25 (mol)
VH2 (đkc)= 0,15. 24,79 = 3,718(l)
\(n_{Mg}=\dfrac{3,6}{24}=0,15mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,15 0,3 0,15 0,15
\(m_{MgCl_2}=0,15\cdot95=14,25g\)
\(V_{H_2}=0,15\cdot22,4=3,36l\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a,PTHH:Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\\ n_{H_2}=n_{\left(CH_3COO\right)_2Mg}=n_{Mg}=0,2\left(mol\right);n_{CH_3COOH}=2.0,2=0,4\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Mg}=142.0,2=28,4\left(g\right)\\ d,m_{ddCH_3COOH}=\dfrac{0,4.60.100}{12}=200\left(g\right)\)