Bài1:Hoà tan hoàn toàn x g Mg vừa đủ trong 110ml dd HCl 1,5M. Tính x? Bài2:Cho 20,25g Al tan hoàn toàn vừa đủ trong x g dd H2SO4 18,735 a,Tính x? b,Nồng độ % của dd thu đc sau phản ứng Bài3:Cho hỗn hợp X gồm 0,1mol Cu và 0,1mol K vào nước dư. Sau phản ứng thu đc dd A và m am chất rắn.Tính giá trị của m? Mong mọi người giải giúp em
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a) Gọi số mol Al, Zn là a, b (mol)
=> 27a + 65b = 11,9 (1)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a----------------->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b------>b------------------>b
=> 1,5a + b = 0,4 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{11,9}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{11,9}.100\%=54,622\%\end{matrix}\right.\)
b) nH2SO4 = 1,5a + b = 0,4 (mol)
=> mH2SO4 = 0,4.98 = 39,2 (g)
=> \(C\%_{dd.H_2SO_4}=\dfrac{39,2}{150}.100\%=26,133\%\)
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
a, \(n_{H_2SO_4}=0,45.0,2=0,09\left(mol\right)\)
PTHH: FeO + H2SO4 → FeSO4 + H2O
Mol: a a
PTHH: MgO + H2SO4 → MgSO4 + H2O
Mol: b b
Ta có: \(\left\{{}\begin{matrix}72a+40b=4,48\\a+b=0,09\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,0275\\b=0,0625\end{matrix}\right.\)
\(\%m_{FeO}=\dfrac{0,0275.72.100\%}{4,48}=44,196\%\)
\(\%m_{MgO}=100-44,196=55,804\%\)
b,
PTHH: FeO + H2SO4 → FeSO4 + H2O
Mol: 0,0275 0,0275
PTHH: MgO + H2SO4 → MgSO4 + H2O
Mol: 0,0625 0,0625
\(C_{M_{ddFeSO_4}}=\dfrac{0,0275}{0,2}=0,1375M\)
\(C_{M_{ddMgSO_4}}=\dfrac{0,0625}{0,2}=0,3125M\)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
BTNT, có: \(n_{SO_4}=n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\)
Mà: m muối = mKL + mSO4
⇒ m = mKL = 93,6 - 0,6.96 = 36 (g)
Bạn tham khảo nhé!
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
b, Gọi: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}+2n_{Mg}=2x+2y\left(mol\right)\\n_{H_2}=n_{Fe}+n_{Mg}=x+y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{HCl}=36,5.\left(2x+2y\right)=73\left(x+y\right)\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{73\left(x+y\right)}{20\%}=365\left(x+y\right)\left(g\right)\)
Ta có: m dd sau pư = mFe + mMg + m dd HCl - mH2 = 56x + 24y + 365.(x+y) - 2.(x+y) = 419x + 387y (g)
Theo PT: \(n_{MgCl_2}=n_{Mg}=y\left(mol\right)\)
\(C\%_{MgCl_2}=11,87\%\) \(\Rightarrow\dfrac{95y}{419x+387y}=0,1187\)
\(\Rightarrow\dfrac{x}{y}=0,9865\Rightarrow x=0,9865y\)
Theo PT: \(n_{FeCl_2}=n_{Fe}=x\left(mol\right)\)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{127x}{419x+387y}.100\%=\dfrac{127.0,9865y}{419.0,9865y+387y}.100\%\approx15,65\%\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}\cdot0,11\cdot1,5=0,0825\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,0825\cdot24=1,98\left(g\right)\)
Bài 3:
Vì Cu không tác dụng với nước
\(\Rightarrow m=m_{Cu}=0,1\cdot64=6,4\left(g\right)\)