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a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<-----------0,01-------->0,01
=> VH2 = 0,01.22,4 = 0,224 (l)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)
b)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,02------>0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)
đổi 200 ml = 0,02 l
a) PTHH : Fe + HCl -> FeCl2 + H2
b) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(=>V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(C_{HCl}=\dfrac{n}{V}=\dfrac{0,1}{0,02}=5\left(M\right)\)
Đông Hải làm câu 1 rồi thì tui làm phần còn lại
Câu 2:
\(a,PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ b,n_{CuO}=\dfrac{m}{M}=\dfrac{8}{80}=0,1\left(mol\right)\\ Theo.PTHH:n_{Cu}=n_{H_2}=n_{CuO}=0,1\left(mol\right)\\ V_{H_2\left(đktc\right)}=n.22,4=0,1.22,4=2,24\left(l\right)\\ c,m_{Cu}=n.M=0,1.64=6,4\left(g\right)\\ d,PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\left(2\right)\\ Theo.PTHH\left(2\right):n_{H_2O}=n_{H_2}=0,1\left(mol\right)\)
\(m_{H_2O}=n.M=0,1.18=1,8\left(g\right)\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{2,84}{142}=0,02\left(mol\right)\)
PTHH :
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,04 0,02 0,02
\(a,C_M=\dfrac{n}{V}=\dfrac{0,04}{0,1}=0,4M\)
\(b,V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(c,PTHH:\)
\(CH_3COOH+C_2H_5OH\underrightarrow{t^o,H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
0,04 0,04
\(m_{este}=0,04.90\%.88=3,168\left(g\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1---->0,1----------------->0,1
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\end{matrix}\right.\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,25 > 0,1 => CuO dư
Theo pthh: nCu = nH2 = 0,1 (mol)
=> mCu = 0,1.64 = 6,4 (g)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,2
\(V_{H_2}=0,2.22,4=4,48l\\
C_M=\dfrac{0,2}{0,2}=1M\\
n_{CuO}=\dfrac{20}{80}=0,25\left(G\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:0,25>0,1\)
=>CuO dư
\(n_{Cu}=n_{H_2}=0,1\left(mol\right)\\
m_{Cu}=0,1.64=6,4g\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\\a, 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b,n_{H_2}=\dfrac{3}{6}.0,6=0,3\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,n_{Al}=n_{AlCl_3}=\dfrac{2}{6}.0,6=0,2\left(mol\right)\\ m_{Al}=0,2.27=5,4\left(g\right)\\ d,V_{ddAlCl_3}=V_{ddHCl}=0,3\left(l\right)\\ C_{MddHCl}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)
200ml = 0,2l
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,3 0,6 0,3 0,3
a) \(n_{ZnCl2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(C_{M_{ZnCl2}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
b) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)
c) Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)
1 1 1 1
0,6 0,6
\(n_{NaOH}=\dfrac{0,6.1}{1}=0,6\left(mol\right)\)
\(m_{NaOH}=0,6.40=24\left(g\right)\)
\(m_{ddNaOH}=\dfrac{24.100}{20}=120\left(g\right)\)
Chúc bạn học tốt
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<------------0,01----->0,01
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,05}=0,4M\)
b) VH2 = 0,01.22,4 = 0,224 (l)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a,Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{MgCl_2}=n_{H_2}=n_{Mg}=0,2\left(mol\right);n_{HCl}=0,2.2=0,4\left(mol\right)\\ b,C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)
