Cho 2,7g Al tác dụng với dung dịch HCl 2M (vừa đủ) A. Tính thể tích khi thoát ra (đktc)? B. Tính nồng độ mol của chất có trong dung dịch sau khi phản ứng kết thúc?
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\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)
\(n_{Al}=\dfrac{4.5}{27}=\dfrac{1}{6}\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\dfrac{1}{6}.....0.5.......\dfrac{1}{6}.......0.25\)
\(m_{HCl}=0.5\cdot36.5=18.25\left(g\right)\)
\(m_{AlCl_3}=\dfrac{1}{6}\cdot133.5=22.25\left(g\right)\)
\(V_{H_2}=0.25\cdot22.4=5.6\left(l\right)\)
\(n_{Al}=\frac{10,8}{27}=0,4\left(mol\right)\)
\(2Al+6HCl->2AlCl_3+3H_2\) (1)
theo (1) \(n_{H_2}=\frac{3}{2}n_{Al}=0,6\left(mol\right)\)
=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)
Cho 10,08 g nhom tac dung vua du voi dung dich axit HCl.2M
a) viet phuong trinh phan ung va tinh the tich H2(dktc)
b) tinh the tich dung dich axit HCl.2M da dung
\(n_{Zn}=\frac{13}{65}=0,2mol\)
\(PTHH:\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0,2\rightarrow0,4\rightarrow0,2\rightarrow0,2\left(mol\right)\)
a)\(V_{H_2}=n_{H_2}.22,4=0,2.22,4=4,48\left(l\right)\)
b)\(m_{ddspư}=m_{Zn}+m_{ddHCl}-m_{H_2}\)
\(=13+100-0,2.1=112,8\left(gam\right)\)
\(C\%_{ddspư}=\frac{m_{ZnCl_2}.100}{m_{ddspư}}=\frac{0,2.136.100}{112,8}\approx24,1\left(\%\right)\)
a)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{175.14,6}{100}=25,55\left(g\right)\\ \rightarrow n_{HCl}=\dfrac{25,55}{35,5}=0,7\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
bđ 0,3 0,7
pư 0,3 0,6
spư 0 0,1 0,3 0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b)
mdd = 16,8 + 175 - 0,3.2 = 191,2 (g)
=> \(\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,93\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{191,2}.100\%=1,91\%\end{matrix}\right.\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{\dfrac{175.14,6}{100}}{36,5}=0,7\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(LTL:\dfrac{0,3}{1}< \dfrac{0,7}{2}\)
\(n_{H_2}=n_{Fe}=0,3\left(mol\right)\\
V_{H_2}=0,3.22,4=6,72\left(l\right)\\
m_{\text{dd}}=16,8+175-\left(0,3.2\right)=191,2\left(g\right)\\
n_{FeCl_2}=n_{Fe}=0,3\left(mol\right)\\
C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,92\%\)
=> HCl dư
Sửa đề: 8,4 gam Fe
\(a,n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ n_{HCl}=\dfrac{14,6.175}{36,5.100}=0,7\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
ban đầu 0,15 0,7
phản ứng 0,15 0,3
sau pư 0 0,4 0,15 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
\(b,m_{dd}=8,4+175-0,15.2=183,1\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{183,1}.100\%=10,4\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,4.36,5}{183,1}.100\%=7,97\%\end{matrix}\right.\)
`n_[Al]=[2,7]/27=0,1(mol)`
`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`
`0,1` `0,3` `0,1` `0,15` `(mol)`
`a)V_[H_2]=0,15.22,4=3,36(l)`
`b)V_[dd HCl]=[0,3]/2=0,15(l)`
`=>C_[M_[AlCl_3]]=[0,1]/[0,15]~~0,67(M)`
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,3 0,1 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ V_{HCl}=\dfrac{0,3}{2}=0,15\left(l\right)\\ C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}M\)