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a. \(n_{Fe_3O_4}=\dfrac{6,96}{232}=0,03\left(mol\right)\)
PTHH : 3Fe + 2O2 -to-> Fe3O4
0,09 0,06 0,03
\(m_{Fe}=0,09.56=5,04\left(g\right)\)
\(V_{O_2}=0,06.22,4=1,344\left(l\right)\)
b. PTHH : 2KCl + 3O2 -> 2KClO3
0,06 0,04
\(m_{KClO_3}=0,04.122,5=4,9\left(g\right)\)
a,b,
\(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\)
PTHH: 2KClO3 --to, MnO2--> 2KCl + 3O2
0,1-------------------->0,1------->0,15
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=0,15.22,4=3,36\left(l\right)\\m_{KCl}=74,5.0,1=7,45\left(g\right)\end{matrix}\right.\)
c, PTHH: 3Fe + 2O2 --to--> Fe3O4
0,225<-0,15------->0,075
=> mFe3O4 = 0,075.232 = 17,4 (g)
nKClO3 = 4,9/122,5 = 0,04 (mol)
PTHH: 2KClO3 -> (t°, MnO2) 2KCl + 3O2
Mol: 0,04 ---> 0,04 ---> 0,06
mKCl = 0,04 . 74,5 = 2,98 (g)
VO2 = 0,06 . 22,4 = 1,344 (l)
4Na + O2 -> (t°) 2Na2O
0,24 <--- 0,06
mNa = 0,24 . 23 = 5,52 (g)
a)\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(m\right)\)
\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
tỉ lệ :2 1 1 1
số mol :0,2 0,1 0,1 0,1
\(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
b)\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(m\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{ }Fe_3O_4\)
theo phương trình ta có tỉ lệ\(\dfrac{0,2}{3}>\dfrac{0,1}{2}\)=>Fe dư
\(PTHH:3Fe+2O_2\xrightarrow[]{}Fe_3O_4\)
tỉ lệ :3 2 1
số mol :0,15 0,1 0,05
\(m_{Fe_3O_4}=0,05.232=11,6\left(g\right)\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 0,25.........0,5.........0,25.......0,25\left(mol\right)\\ a.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b.m_{HCl}=0,5.36,5=18,25\left(g\right)\\ c.n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\ Fe_2O_3+3H_2\underrightarrow{^{to}}2Fe+3H_2O\\ Vì:\dfrac{0,25}{3}< \dfrac{0,1}{1}\\ \Rightarrow Fe_2O_3dư\\ n_{Fe}=\dfrac{2}{3}.0,25=\dfrac{1}{6}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{1}{6}.56\approx9,333\left(g\right)\)
a,\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,25 0,5 0,25
\(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b,\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
c,\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,25 \(\dfrac{1}{6}\)
Ta có: \(\dfrac{0,1}{1}>\dfrac{0,25}{3}\)⇒ Fe2O3 dư, H2 hết
\(m_{Fe}=\dfrac{1}{6}.56=9,33\left(g\right)\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
a/ Ta có: \(n_{KClO_3}=\dfrac{12.25}{122.5}=0.1\left(mol\right)\)
PTHH:
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
2 3
0.1 x
\(=>x=\dfrac{0.1\cdot3}{2}=0.15=n_{O_2}\)
\(=>V_{O_2}=0.15\cdot22.4=3.36\left(l\right)\)
PTHH: \(KClO_3\underrightarrow{t^o}KCl+\dfrac{3}{2}O_2\)
a) Ta có: \(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\)
\(\Rightarrow n_{O_2}=0,15\left(mol\right)\) \(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
b) PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,15}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\) \(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\)