Đốt cháy m gam Al trong oxi dư thu được Al2O3. Hòa tan hết lượng Al2O3 trên cần dùng 240 gam dung
dịch HCl 7,3% được dung dịch X.
1.Viết các PTPU ?
2.Tính m? Tính C% chất tan trong dung dịch X?
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a) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 4Al + 3O2 ---to→ 2Al2O3
Mol: 0,1 0,075 0,05
\(V_{O_2}=0,075.22,4=1,68\left(l\right)\)
b) \(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
c)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,05 0,3 0,1
\(m_{ddHCl}=\dfrac{0,3.36,5.100}{7,3}=150\left(g\right)\)
\(n_{HCl}=\dfrac{192.7,3}{100.36,5}=0,384\left(mol\right)\)
PTHH: NaOH + HCl --> NaCl + H2O
______0,384<-0,384->0,384____________(mol)
=> mNaOH = 0,384.40 = 15,36 (g)
=> \(m_{DD}=\dfrac{15,36.100}{20}=76,8\left(g\right)\)
\(C\%\left(NaCl\right)=\dfrac{0,384.58,5}{76,8+192}.100\%=8,36\%\)
\(n_{HCl}=\dfrac{192.7,3\%}{100\%.36,5}=0,384(mol)\\ PTHH:NaOH+HCl\to NaCl+H_2O\\ \Rightarrow n_{NaOH}=n_{HCl}=0,384(mol)\\ \Rightarrow m=m_{dd_{NaOH}}=\dfrac{0,384.40}{20\%}=76,8(g)\\ n_{NaCl}=n_{HCl}=0,384(mol)\\ \Rightarrow C\%_{NaCl}=\dfrac{0,384.58,5}{76,8+192}.100\%=8,36\%\)
a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2<---0,6<--------------0,3
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,2.27}{15,6}.100\%=34,615\%\\\%Al_2O_3=\dfrac{15,6-0,2.27}{15,6}.100\%=65,385\%\end{matrix}\right.\)
b) \(n_{Al_2O_3}=\dfrac{15,6-0,2.27}{102}=0,1\left(mol\right)\)
PTHH: Al2O3 + 6HCl --> 2AlCl3 + 3H2O
______0,1--->0,6
=> nHCl = 0,6+0,6 = 1,2(mol)
=> \(V_{dd}=\dfrac{1,2}{2}=0,6\left(l\right)\)
a)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
_____0,1<---0,2<-------0,1<---0,1
=> mHCl = 0,2.36,5 = 7,3 (g)
=> \(m_{ddHCl}=\dfrac{7,3.100}{7,3}=100\left(g\right)\)
mdd sau pư = 0,1.24 + 100 - 0,1.2 = 102,2 (g)
\(C\%\left(MgCl_2\right)=\dfrac{0,1.95}{102,2}.100\%=9,2955\%\)
b)
CTHH: AaOb
PTHH: \(A_aO_b+2bHCl->aACl_{\dfrac{2b}{a}}+bH_2O\)
____________0,2------->\(\dfrac{0,1a}{b}\)
=> \(\dfrac{0,1a}{b}\left(M_A+35,5.\dfrac{2b}{a}\right)=13,5\)
=> \(M_A=\dfrac{64b}{a}=\dfrac{2b}{a}.32\)
Nếu \(\dfrac{2b}{a}=1\) => MA = 32 (L)
Nếu \(\dfrac{2b}{a}=2\) => MA = 64(Cu)
\(1,PTHH:4Al+3O_2\xrightarrow{t^o}2Al_2O_3\\ Al_2O_3+6HCl\to 2AlCl_3+3H_2\\ 2,n_{HCl}=\dfrac{240.7,3\%}{100\%.36,5}=0,48(mol)\\ \Rightarrow n_{Al_2O_3}=\dfrac{1}{6}n_{HCl}=0,08(mol)\\ \Rightarrow n_{Al}=2n_{Al_2O_3}=0,16(mol)\\ \Rightarrow m_{Al}=0,16.27=4,32(g)\\ n_{H_2}=\dfrac{1}{2}n_{HCl}=0,24(mol)\\ n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,16(mol)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,16.133,5}{0,08.102+240-0,24.2}.100\%=8,62\%\)