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nFe = 16.8/56 = 0.3 (mol)
3Fe + 2O2 -to-> Fe3O4
0.3......0.2...........0.1
VO2 = 0.2*22.4 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 (g)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
a) PTHH : \(2Zn+O_2-t^o->2ZnO\)
b) \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Theo PTHH : \(n_{O2}=\dfrac{1}{2}n_{Zn}=0,15\left(mol\right)\)
=> \(V_{O2}=0,15.22,4=3,36\left(l\right)\)
c) Theo PTHH : \(n_{ZnO}=n_{Zn}=0,3\left(mol\right)\)
=> \(m_{ZnO}=0,3.81=24,3\left(g\right)\)
vậy ...
\(\begin{array}{l} a,\ PTHH:2Zn+O_2\xrightarrow{t^o} 2ZnO\\ b,\\ n_{Zn}=\dfrac{19,5}{65}=0,3\ (mol)\\ Theo\ pt:\ n_{O_2}=\dfrac{1}{2}n_{Zn}=0,15\ (mol)\\ \Rightarrow V_{O_2}=0,15\times 22,4=3,36\ (l)\\ c,\\ Theo\ pt:\ n_{ZnO}=n_{Zn}=0,3\ (mol)\\ \Rightarrow m_{ZnO}=0,3\times 81=24,3\ (g)\end{array}\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
PTHH: \(Cu_2S+2O_2\xrightarrow[]{t^o}2CuO+SO_2\)
a) Ta có: \(n_{Cu_2S}=\dfrac{100}{160}=0,625\left(mol\right)\) \(\Rightarrow n_{O_2\left(lýthuyết\right)}=1,25\left(mol\right)\)
\(\Rightarrow V_{O_2\left(thực\right)}=\dfrac{1,25\cdot22,4}{96\%}\approx29,17\left(l\right)\)
b) Sửa đề: "Tính khối lượng KMnO4 để hấp thụ hết SO2"
PTHH: \(5SO_2+2KMnO_4+2H_2O\rightarrow K_2SO_4+2MnSO_4+2H_2SO_4\)
Ta có: \(n_{SO_2\left(thực\right)}=n_{Cu_2S}\cdot96\%=0,6\left(mol\right)\)
\(\Rightarrow n_{KMnO_4}=0,24\left(mol\right)\) \(\Rightarrow m_{KMnO_4}=0,24\cdot158=37,92\left(g\right)\)
c) PTHH: \(SO_2+\dfrac{1}{2}O_2\xrightarrow[V_2O_5]{t^o}SO_3\)
Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{SO_2}=0,3\left(mol\right)\) \(\Rightarrow V_{kk}=\dfrac{0,3\cdot22,4}{21\%}=32\left(l\right)\)
d) Bảo toàn nguyên tố Lưu huỳnh: \(n_{H_2SO_4\left(lýthuyết\right)}=n_{SO_2\left(thực\right)}=0,3\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(thực\right)}=0,3\cdot85\%=0,255\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,255\cdot98}{10\%}=249,9\left(g\right)\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,2mol\\n_{Fe_3O_4}=0,1mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4}=0,1\cdot232=23,2\left(g\right)\\V_{O_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)