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a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
b) PTHH: \(2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=0,2\cdot2,5=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,5}{1}\) \(\Rightarrow\) CuSO4 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{Cu\left(OH\right)_2}=0,1\left(mol\right)=n_{Na_2SO_4}\\n_{CuSO_4\left(dư\right)}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\\C_{M_{Na_2SO_4}}=\dfrac{0,1}{0,4+0,2}\approx0,17\left(M\right)\\C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0,4}{0,6}\approx0,67\left(M\right)\end{matrix}\right.\)
Bài 1 :
a) $2Na + 2H_2O \to 2NaOH + H_2$
b) $n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol) \Rightarrow n_{Na} = 2n_{H_2} = 0,5(mol)$
$m_{Na} = 0,5.23 = 11,5(gam)$
c) $n_{NaOH} = n_{Na} = 0,5(mol)$
$C_{M_{NaOH}} = \dfrac{0,5}{0,2} = 2,5M$
$m_{H_2O} = D.V = 200.1 = 200(gam)$
$m_{dd} = 11,5 + 200 - 0,25.2 = 211(gam)$
$C\%_{NaOH} = \dfrac{0,5.40}{211}.100\% = 9,48\%$
Bài 2:
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{11,2.20\%}{22,4}=0,1\left(mol\right)\\ 4Al+3O_2\underrightarrow{^{to}}2Al_2O_3\\ Vì:\dfrac{0,1}{4}< \dfrac{0,3}{1}\Rightarrow O_2dư\\ \Rightarrow Sau.p.ứng:Al_2O_3,O_2dư,N_2\\ n_{N_2}=\dfrac{80}{20}.0,1=0,4\left(mol\right)\Rightarrow m_{N_2}=28.0,4=11,2\left(g\right)\\ n_{O_2\left(dư\right)}=0,1-\dfrac{3}{4}.0,1=0,025\left(mol\right)\\ m_{O_2\left(dư\right)}=0,025.32=0,8\left(g\right)\\ n_{Al_2O_3}=\dfrac{2}{4}.0,1=0,05\left(mol\right)\\ m_{Al_2O_3}=102.0,05=5,1\left(g\right)\)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.2Na+2H_2O\rightarrow2NaOH+H_2\\ b.0,5.......0,5.........0,5..........0,25\left(mol\right)\\ b.m_{Na}=0,5.23=11,5\left(g\right)\\ c.C\%_{ddA}=C\%_{ddNaOH}=\dfrac{0,5.40}{0,5.23+200.1-0,25.2}.100\approx9,479\%\)
a) Đổi 300 ml = 0,3 l
Cm=\(\dfrac{n}{v}\) \(\Rightarrow\) nNaOH= Cm.V = 0,3.1 = 0,3 Mol
PTHH: 2NaOH + FeCl2 \(\rightarrow\) 2NaCl + Fe(OH)2
\(\Rightarrow\) nFe = 0,3 Mol
\(\Rightarrow\) VFe = \(\dfrac{n}{Cm}\) = \(\dfrac{0,3}{0,1}\) = 3 lít
b) ta có n\(_{Fe\left(OH\right)_2}\)= 0,3 Mol
\(\Rightarrow\) m\(_{Fe\left(OH\right)_2}\)= n.M = 0,3.90 = 27 g
c) mk nghĩ phải cho VNaCl mới giải đc
V = 300 ml = 0,3 (l)
=>nNaOH = 0,3.1 = 0,3 mol
2NaOH + FeCl2 ->2 NaCl + Fe(OH)2
0,3------>0,15---->0,3--------0,15
a) VFeCl2 = \(\dfrac{0,15}{0,1}\)= 1,5 (l)
b) mFe(OH)2 = 0,15 . 90 = 13,5 g
c) Vdd = 1,5+ 0,3 = 1,8 (l)
CM(NaCl) = \(\dfrac{0,3}{1,8}\) = 0,1666 M
\(a.PTHH:Fe_2O_3+6HCl--->2FeCl_3+3H_2O\)
b. Ta có: \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=6.n_{Fe_2O_3}=6.0,1=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
c. Theo PT: \(n_{FeCl_3}=2.n_{Fe_2O_3}=0,1.2=0,2\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=0,2.162,5=32,5\left(g\right)\)
Ta có: \(m_{dd_{FeCl_3}}=16+284=300\left(g\right)\)
\(\Rightarrow C_{\%_{FeCl_3}}=\dfrac{32,5}{300}.100\%=10,83\%\)
nFe2O3= 0.1(mol)
PTHH: Fe2O3 + 6HCl -> 2FeCl3 + 3H2O (1)
a) Theo PT (1) : nHCl = 6 nFe2O3 -> nHCl = 0.1*6= 0.6(mol)
=> mHCl= 0.6*36.5 = 21.9(g)
b)nFeCl3=0.2(mol)
mFeCl3= 162.5*0.2=32.5(g)
=> mdd sau phản ứng: 248+16 = 264(g)
=> C%muối= 32.5:264*100=12.3%
\(m_{Fe_2\left(SO_4\right)_3}=\dfrac{200\cdot20}{100}=40\left(g\right)\Rightarrow n=0,1mol\)
\(Fe_2\left(SO_4\right)_3+6NaOH\rightarrow2Fe\left(OH\right)_3\downarrow+3Na_2SO_4\)
0,1 0,6 0,2 0,3
a)\(m_{NaOH}=0,6\cdot40=24\left(g\right)\)
b)\(m_{Fe\left(OH\right)_3}=0,2\cdot107=21,4\left(g\right)\)
c)\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
\(m_{ddsau}=200+24-21,4=202,6\left(g\right)\)
\(\Rightarrow C\%=\dfrac{42,6}{202,6}\cdot100\%=21,03\%\)
Đáp án C
,nFeCl2 = 0,1 ; nAgNO3 = 0,5 mol
Fe2+ + Ag+ -> Fe3+ + Ag
Ag+ + Cl- -> AgCl
=> kết tủa gồm 0,2 mol AgCl và 0,1 mol Ag
=> mkết tủa = 39,5g
=>C
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) Pt : \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,25 0,5 0,25
b) \(n_{Fe\left(OH\right)2}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
⇒ \(m_{Fe\left(OH\right)2}=0,25.90=22,5\left(g\right)\)
c) \(n_{FeCl2}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddFeCl2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
d) Pt : \(Fe\left(OH\right)_2\underrightarrow{t^o}FeO+H_2O|\)
1 1 1
0,25 0,25
\(n_{FeO}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)
⇒ \(m_{FeO}=0,25.72=18\left(g\right)\)
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