Hòa tan 2,7 gam nhôm trong dung dịch axit sunfuric H2SO4 9,8% thu được V (lít) khí và dung dịch A.
a) Tính V (đktc)?
b) Tính khối lượng dung dịch H2SO4 9,8% cần dùng.
c) Tính nồng độ % dung dịch thu được sau phản ứng.
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a, PTPƯ: SO3 + H2O ---> H2SO4
nSO3=\(\dfrac{2,24}{22,4}=0,1mol\)
1 mol SO3 ---> 0,1 mol H2SO4
nên 0,1 mol SO3 ---> 0,1 mol H2SO4
CM H2SO4=\(\dfrac{0,1}{0,5}\)=0,2 M
b, PTPƯ: Zn + H2SO4 ---> ZnSO4 + H2
1 mol H2SO4 ---> 1 mol Zn
nên 0,1 mol H2SO4 ---> 0,1 mol Zn
mZn=0,1.65=6,5 g
\(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\\ m_{H_2SO_4}=9,8\%.40=3,92\left(g\right)\\ n_{H_2SO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,02}{2}< \dfrac{0,04}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,02=0,03\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,02=0,01\left(mol\right)\end{matrix}\right.\)
\(\rightarrow V_{H_2}=0,03.22,4=0,672\left(l\right)\\ m_{dd}=0,54+40=40,54\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,01}{40,54}=8,43\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{\left(0,04-0,03\right).98}{40,54}=2,41\%\end{matrix}\right.\)
`Fe + H_2 SO_4 -> FeSO_4 + H_2 ↑`
`0,3` `0,3` `0,3` `0,3` `(mol)`
`n_[Fe] = [ 16,8 ] / 56 = 0,3 (mol)`
`a) m_[dd H_2 SO_4] = [ 0,3 . 98 ] / [ 9,8 ] . 100 = 300 (g)`
`b) V_[H_2] = 0,3 . 22,4 = 6,72 (l)`
`c) C%_[FeSO_4] = [ 0,3 . 152 ] / [ 16,8 + 300 - 0,3 . 2 ] . 100 ~~ 14,42%`
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)
\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,15 0 ,05 0,15
a)\(V=0,15\cdot22,4=3,36\left(l\right)\)
b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,7}{9,8}\cdot100=150\left(g\right)\)
c) \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)
\(m_{ddsau}=2,7+150-0,3=152,4\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\)
\(\Rightarrow C\%=\dfrac{17,1}{152,4}\cdot100=11,22\%\)