Câu 1 : Hoàn thành sơ đồ phản ứng
a , MnO2 \(\rightarrow\)Cl2\(\rightarrow\) HCl\(\rightarrow\)NaCl\(\rightarrow\)Cl2\(\rightarrow\)H2SO4\(\rightarrow\)HCl
b , BaCl2\(\rightarrow\)Cl2\(\rightarrow\)HCl\(\rightarrow\)FeCl2\(\rightarrow\)FeCl3\(\rightarrow\)BaCl2\(\rightarrow\)HCl
c , BaCl2\(\rightarrow\)HCl\(\rightarrow\)CuCl2\(\rightarrow\)KCl\(\rightarrow\)KOH\(\rightarrow\)KClO3\(\rightarrow\)Cl2
a) (1) MnO2 + 4 HCl(đặc) -to-> MnCl2 + Cl2 + 2 H2O
(2) Cl2 + H2 \(\Leftrightarrow\) 2 HCl
(3) HCl + NaOH -> NaCl + H2O
(4) 2 NaCl + 2 H2O -đpddcmnx-> 2 NaOH + H2 + Cl2
(5) Cl2 + 2 H2O + SO2 -> H2SO4 + 2 HCl
(6) H2SO4 + BaCl2 -> BaSO4 + 2 HCl
b)
(1) BaCl2 -điện phân nóng chảy nhiệt độ cao-> Ba + Cl2
(2) Cl2 + H2 \(\Leftrightarrow\) 2 HCl
(3) Fe + 2 HCl -> FeCl2 + H2
(4) 2 FeCl2 + Cl2 -to-> 2 FeCl3
(5) 2 FeCl3 + 3 Ba(OH)2 -> 2 Fe(OH)3 +3 BaCl2
(6) BaCl2 + H2SO4 -> BaSO4 + 2 HCl
c) (1) BaCl2 + H2SO4 -> BaSO4 +2 HCl
(2) 2 HCl + CuO -> CuCl2 + H2O
(3) CuCl2 + 2 KOH -> Cu(OH)2 + 2 KCl
(4) KCl + H2O -đpddcmnx-> KOH + 1/2 Cl2 + 1/2 H2
(5) 6 KOH + 3 Cl2 -to->5 KCl + KClO3 +3 H2O
(6) 2 KClO3 -to-> 2 KCl + 3 O2
a)
(1) MnO2 + 4HCl(đ) -to-> MnCl2 + Cl2 + 2H2O
(2) Cl2 + H2 <-as-> 2 HCl
(3) HCl + NaOH => NaCl + H2O
(4) 2NaCl + 2H2O -đpddcmn-> 2NaOH + H2 + Cl2
(5) Cl2 + 2H2O + SO2 => H2SO4 + 2HCl
(6) H2SO4 + BaCl2 => BaSO4 + 2HCl
b)
(1) BaCl2 -đpdd-> Ba + Cl2
(2) Cl2 + H2 ⇔ 2HCl (Đk : ánh sáng hoặc nhiệt độ)
(3) Fe + 2HCl => FeCl2 + H2
(4) 2FeCl2 + Cl2 -to-> 2FeCl3
(5) 2FeCl3 + 4Ba(OH)2 => 2Fe(OH)3 + 3BaCl2
(6) BaCl2 + H2SO4 => BaSO4 + 2HCl
c)
(1) BaCl2 + H2SO4 => BaSO4 +2HCl
(2) 2HCl + CuO => CuCl2 + H2O
(3) CuCl2 + 2KOH => Cu(OH)2 + 2KCl
(4) 2KCl + 2H2O -đpddcmn-> 2KOH + Cl2 + H2
(5) 6KOH + 3Cl2 -to-> 5KCl + KClO3 +3H2O
(6) 2KClO3 -to-> 2KCl + 3O2