Trộn 200ml dung dịch H2SO4 0,5M với 300ml dung dịch H2SO4 1M thu được dung dịch X
a) tính CM dung dịch X
b) Tính khối lượng dung dịch NaOH 20% cần để trung hòa dung dịch X
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\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ PTHH:2NaOH+H_2SO_4\to Na_2SO_4+2H_2O\\ a,n_{NaOH}=0,4(mol);n_{Na_2SO_4}=0,2(mol)\\ \Rightarrow \begin{cases} m_{Na_2SO_4}=0,2.142=28,4(g)\\ m_{dd_{NaOH}}=\dfrac{0,4.40}{20\%}=80(g) \end{cases}\\ b,2KOH+H_2SO_4\to K_2SO_4+2H_2O\\ \Rightarrow n_{KOH}=0,4(mol)\\ \Rightarrow m_{dd_{KOH}}=\dfrac{0,4.56}{5,6\%}=400(g)\\ \Rightarrow V_{dd_{KOH}}=\dfrac{400}{1,045}=382,78(ml)\)
Bước 1: nH2SO4 = VH2SO4 . CM H2SO4= 0,2 . 1 = 0,2mol
Bước 2:
PTHH: 2NaOH + H2SO4 → Na2SO4 + H2O
2 mol 1 mol
? mol 0,2mol
nNaOH=0,2.21=0,4mol.nNaOH=0,2.21=0,4mol.
m NaOH= n NaOH.MNaOH = 0,4 . (23 + 16 + 1) = 16g
Bước 3: C% = mNaOH : m dd NaOH => mdd NaOH = mNaOH : C% = 16 : 20% = 80g
\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)
\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.1..........0.05...............0.05\)
Dung dịch D : 0.05 (mol) K2SO4 , 0.1 (mol) H2SO4
\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)
\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)
\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.2..................0.1\)
\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)
a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)
\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)
0,2.............0,1
Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư
Dung dịch D gồm NaNO3 và NaOH dư
\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)
\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)
\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
Ion trong dung dịch D : Na+ , NO3-, OH-
\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)
\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)
\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)
b)Trong dung dịch D chỉ có NaOH dư phản ứng
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
0,1................0,05
=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)
Đáp án : C
Bảo toàn e : 2nH2 = 3nAl+ + 2nFe2+ = 0,5 mol
=> nH+ dư = nHCl + 2nH2SO4 – 2nH2 = 0,1 mol
Để đạt kết tủa lớn nhất : nOH = nH+ + 3nAl+ + 2nFe2+ = 0,6 mol
=> Vdd NaoH = 0,6 lit = 600 ml
NaOH + HCl --> NaCl+H2O (1)
2NaOH +H2SO4 --> Na2SO4 +2H2O (2)
Đặt nNaOH (1)= a(mol)
nNaOH(2) = b (mol)
=>a + b = 0,3.2 =0,6( *)
Theo PT (1) : nNaCl = nNaOH(1) = a(mol)
Theo PT (2) : nNa2SO4=\(\dfrac{1}{2}\) nNaOH(2) = 0,5b(mol)
=>58,5a + 71b =40,1(**)
Từ (*), (**) => a= 0,2 ; b = 0,4
nHCl = nNaOH (1)=0,2 mol
=> \(x=CM_{HCl}=\dfrac{0,2}{0,2}=1M\)
nH2SO4 = nNaOH (2)=0,4 mol
\(y=CM_{H_2SO_4}=\dfrac{0,4}{0,2}=2M\)
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02........0.02\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)
\(a.\)
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02.......0.02\)
\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)
a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)
b) Ta có: \(pH=14+log\left[OH^-\right]=13\)
c) PT ion: \(OH^-+H^+\rightarrow H_2O\)
Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)
Với 200ml=0.2l dd H2SO4 0.5M => nH2SO4 = 0.2 x 0.5 = 0.1 (mol)
Với 300ml=0.3l dd H2SO4 1M => nH2SO4 = 1x0.3 = 0.3 (mol)
nH2SO4 = 0.1 + 0.3 = 0.4 (mol)
Vdd = 200 + 300 = 500 ml = 0.5 l
CM X = 0.4/0.5 = 0.8 M
H2SO4 + 2NaOH => Na2SO4 + 2H2O
==> nNaOH = 0.8 x 2 = 1.6 M
mNaOH = n.M = 1.6 x 40 = 64 (g)
mddNaOH = 64 x 100/ 20 = 320 (g)