Cho một lượng bột nhôm dư vào 100 gam dung dịch H2SO4 9,8%
a) Tính khối lượng nhôm phản ứng
b) Tính thể tích khí thoát ra ở đktc
c) Tính nồng độ % muối nhôm
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a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ 0,2........0,3...........0,1...........0,3\left(mol\right)\\ a.C_{MddH_2SO_4}=\dfrac{0,3}{0,3}=1\left(M\right)\\ b.m_{Al_2\left(SO_4\right)_3}=342.0,1=34,2\left(g\right)\\ c.V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,3}=1M\)
b) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=n.M=0,1.342=34,2\left(g\right)\)
c) \(n_{H_2}=n_{H_2SO_4}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Làm gộp các phần còn lại
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1mol\\n_{H_2SO_4}=n_{H_2}=0,3mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1,5=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2\cdot27=5,4\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
\(nH_2=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(nH_2SO_4=nH_2=0,15\left(mol\right)\)
\(nH_2SO_{4\left(15\%\right)}=\dfrac{0,15.15}{100}=0,0225\left(mol\right)\)
\(mH_2SO_4=0,0225.98=2,205\left(g\right)\)
\(nAl=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)
\(mAl=0,1.27=2,7\left(g\right)\)
2Al+3H2SO4->Al2(SO4)3+3H2(khí)
mH2SO4=100*9.8:100=9.8(g)
nH2SO4=0.1(mol)
theo pthh:nAl=2/3 nH2SO4->nAl=2/3*0.1=0.07(mol)
mAl=0.07*27=1.89(g)
theo pthh:nH2=nH2SO4->nH2=0.1(mol)
VH2=0.1*22.4=2.24(l)
Theo pthh:nAl2(SO4)3=1/3 nH2SO4->nAl2(SO4)3=0.03(mol)
m muối=0.03*342=10.26(g)
mdd=1.89+100-0.1*2=101.69(g)
C% muối:10.26:101.69*100=10.09%