Cho 9.6 g Na và 9.3 g Na2O vào 100g nc tính nồng độ % của dd thu đc sau pứ
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2. Ta có: mKOH 20% = \(\frac{200.20}{100}\) = 40g
mKOH 10% = mKOH 20% = 40g
=>mdd KOH 10% = \(\frac{40.100}{10}\) = 400g
=> mH2O = 400 - 200 =200g
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}+2n_{Na_2O}=\dfrac{4,6}{23}+2\cdot\dfrac{6,2}{62}=0,3\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3\cdot40=12\left(g\right)\\m_{H_2}=0,05\cdot2=0,1\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na}+m_{Na_2O}+m_{H_2O}-m_{H_2}=110,7\left(g\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{12}{110,7}\cdot100\%\approx10,84\%\)
Câu 1 :
mNaCl = 5.85*100/100= 5.85 g
mH2SO4 = 100*49/100=49 g
mNaOH = 100*20/100=20 g
BaSO4 không tan trong nước nên không tính được
Câu 2 :
nNa = 2.3/23 = 0.1 mol
Na + H2O --> NaOH + 1/2H2
0.1___________0.1______0.05
mdd sau phản ứng = 2.3 + 100 - 0.1 = 102.2 g
mNaOH = 4g
C%NaOH = 4/102.2*100% = 3.91%
Câu 3 :
nCa = 0.05 mol
Ca + 2H2O --> Ca(OH)2 + 2H2
0.05____________0.05_____0.1
mdd = 100 + 2 - 0.2 = 101.8 g
mCa(OH)2 = 3.7 g
C%Ca(OH)2 = 3.63%
Câu 4 :
nH2 = 5*10-5 mol
Ca + 2H2O --> Ca(OH)2 + H2
5*10-5__________5*10-5__5*10-5
mCa = 0.002 g
mCa(OH)2 = 0.0037 g
mdd sau phản ứng = 100 g
C%Ca(OH)2 = 0.0037%
1)
Na2O + H2O --> 2NaOH
0.1 0.2 (mol)
C% =(0,2. 40)/(100 + 6,2) = 7,53%
Câu 1:
\(n_{Na_2O}=\dfrac{6,2}{62}=0,1mol\)
Na2O+H2O\(\rightarrow\)2NaOH
\(n_{NaOH}=2n_{Na_2O}=0,2mol\)
\(C\%_{NaOH}=\dfrac{0,2.40.100}{100+6,2}\approx7,53\%\)
Câu 2:
\(n_{Na}=\dfrac{6,2}{23}mol\)
2Na+2H2O\(\rightarrow\)2NaOH+H2
Số mol NaOH=số mol Na=\(\dfrac{6,2}{23}mol\)
Số mol H2=0,5 số mol Na=\(\dfrac{3,1}{23}mol\)
mdd=6,2+100-\(\dfrac{3,1}{23}.2\approx105,93g\)
\(C\%_{NaOH}=\dfrac{\dfrac{6,2}{23}.40.100}{105,93}\approx10,2\%\)
a) $Mg + 2HCl \to MgCl_2 + H_2$
$n_{MgCl_2} = \dfrac{4,75}{95} = 0,05(mol)$
$n_{HCl} = 2n_{MgCl_2} = 0,1(mol)$
$m_{dd\ HCl} = \dfrac{0,1.36,5}{14,6\%} = 25(gam)$
$\Rightarrow V_{dd\ HCl} = \dfrac{25}{1,12} = 22,32(ml)$
b) $n_{Mg} = n_{H_2} = n_{MgCl_2} = 0,05(mol)$
$\Rightarrow m_{dd\ sau\ pư} = 0,05.24 + 25 - 0,05.2 = 26,1(gam)$
$C\%_{HCl} = \dfrac{4,75}{26,1}.100\% = 18,2\%$
Bài 7 : Theo đề bài ta có : \(\left\{{}\begin{matrix}nNa=\dfrac{m1}{23}mol\\nNa2O=\dfrac{m2}{62}mol\end{matrix}\right.\)
Ta có PTHH 1 :
2Na + 2H2O \(\rightarrow\) 2NaOH + H2
\(\dfrac{m1}{23}mol..........\dfrac{m1}{23}mol..\dfrac{1}{2}.\dfrac{m1}{23}mol\) = \(\dfrac{m1}{46}mol\)
=> mddNaOH = m1 + p - 2.\(\dfrac{m1}{46}=m1+p-\dfrac{m1}{23}\)
mct = mNaOH = 40.\(\dfrac{m1}{23}\) = \(\dfrac{40.m1}{23}\left(g\right)\)
=> a% = \(\dfrac{\dfrac{40m1}{23}}{m1+p-\dfrac{m1}{23}}.100\%=\dfrac{4000m1}{22m1+23p}\%\left(1\right)\)
Ta có PTHH 2 :
Na2O + H2O \(\rightarrow\) 2NaOH
\(\dfrac{m2}{62}mol.........2\dfrac{m2}{62}=\dfrac{m2}{31}mol\)
=> mddNaOH = \(m2+p\) (g)
mct = mNaOH = \(40.\dfrac{m2}{31}=\dfrac{40.m2}{31}\left(g\right)\)
=> a% = \(\dfrac{\dfrac{40m2}{31}}{m2+p}.100\%=\dfrac{4000m2}{31m2+31.p}\) % (2)
Ta có (1) = (2)
<=> \(\dfrac{4000m1}{22m1+23p}\) = \(\dfrac{4000m2}{31m2+31p}\)
<=> 4000m2 ( 22m1 + 23p ) = 4000m1( 31m2 + 31p )
Phần rút gọn dễ nên bạn tự rút gọn nha !
nNaNa=48/115 mol
nNa2ONa2O=0,15 mol
Bảo toàn NaNa nNaOHNaOH=48/115+0,15.2=33/46 mol
=>mNaOHNaOH=660/23 gam
nH2H2=0,5nNaNa=24/115 mol
mdd sau pứ=9,6+9,3+100-48/115=118,4826 gam
C%dd NaOHNaOH=(660/23)/118,4826.100%=24,22%