Hòa tan hoàn toàn 1,08 gam nhôm với dung dịch H2SO4 nồng độ 2M, tạo ra muối và khí H2, thoát ra. Tìm: a/ Thể tích khí H2 (đkc) b/ Thể tích dung dịch H2SO4 cần phản ứng c/ Nồng độ mol dung dịch muối sau phản ứng. Giả sử thể tích dung dịch sau phản ứng không thay đổi
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PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(C_{M_{H_2SO_4}}=\dfrac{0,2}{0,5}=0,4M\)
c)\(C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
pthh : \(Fe+H_2SO_4->FeSO_4+H_2\)
0,2 0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\)
\(m_{H_2SO_4}=\dfrac{0,5}{22,4}.98\approx2,188\left(g\right)\)
=> mdd=11,2+2,188=13,388(g)
C%=\(\dfrac{2,188}{13,388}.100\%=16,3\%\)
Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
nAl = 5.4/27 = 0.2 (mol)
2Al + 3H2SO4 => Al2(SO4)3 + 3H2
0.2____0.3_________________0.3
VH2 = 0.3*22.4 = 6.72(l)
CM H2SO4 = 0.3/0.1 = 3 M
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow n_{H_2}=0,3mol=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{H_2SO_4}}=\dfrac{0,3}{0,1}=3\left(M\right)\end{matrix}\right.\)
nAl= 0,04(mol)
PTHH: 2 Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
0,04___________0,06___0,02_____0,06(mol)
a) V(H2, đktc)=0,06.22,4=1,344(l)
b) VddH2SO4= 0,06/2=0,03(l)=30(ml)
c) VddAl2(SO4)3=VddH2SO4=0,03(l)
=>CMddAl2(SO4)3=0,02/0,03=2/3(M)
\(n_{Al}=\dfrac{1.08}{27}=0.04\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.04......0.06.............0.02...........0.06\)
\(V_{H_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.06}{2}=0.03\left(l\right)\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0.02}{0.03}=\dfrac{2}{3}\left(M\right)\)