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\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ 0,05.........0,1..........0,05..........0,05\left(mol\right)\\ a.C\%_{ddHCl}=\dfrac{0,1.36,5}{200}.100=1,825\%\\ b.m_{Zn}=0,05.65=3,25\left(g\right)\\ c.C\%_{ddZnCl_2}=\dfrac{136.0,05}{3,25+200-0,05.2}.100\approx3,347\%\)
\(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
a) Pt : \(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,2 0,4 0,2
b) \(n_{MgCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{MgCl2}=0,2.95=19\left(g\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
\(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
d) \(m_{ddspu}=8+146=154\left(g\right)\)
\(C_{MgCl2}=\dfrac{19.100}{154}=12,34\)0/0
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\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
\(m_{ct}=\dfrac{10.200}{100}=20\left(g\right)\)
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) Pt : \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O|\)
2 1 1 2
0,5 0,25 0,25
\(n_{H2SO4}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
\(m_{H2SO4}=0,25.98=24,5\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\)
b) \(n_{Na2SO4}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)
⇒ \(m_{Na2SO4}=0,25.142=35,5\left(g\right)\)
\(m_{ddspu}=200+122,5=322,5\left(g\right)\)
\(C_{Na2SO4}=\dfrac{35,5.100}{322,5}=11\)0/0
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