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a) \(n_{SO_3}=\dfrac{m}{M}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: `SO_3 + H_2O -> H_2SO_4`
b) Theo PTHH: `n_{H_2SO_4} = n_{SO_3} = 0,4 (mol)`
`=> m_{H_2SO_4} = 0,4.98 = 39,2 (g)`
2Al + 3H2SO4 -----> Al2(SO4)3 + 3H2
nAl = 7,1/27 = 71/270 ( mol)
=> nH2 = 71/180 ( mol)
=> VH2= 8,86 lit
=> m muối=71\540 .342=44,967g
\(n_{Al}=\dfrac{7,1}{27}=\dfrac{71}{270}\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(\dfrac{71}{270}\) \(\dfrac{71}{540}\) \(\dfrac{71}{180}\)
\(V_{H_2}=\dfrac{71}{540}.22,4=3l\\
m_{Al_2\left(SO_4\right)_3}=342.\dfrac{71}{180}=134,9g\)
a) \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b) \(n_{H_2\left(1\right)}=n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(n_{H_2\left(2\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.\dfrac{2,7}{27}=0,15\left(mol\right)\)
=> \(V=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
c) \(n_{H_2SO_4\left(1\right)}=n_{Mg}=0,2\left(mol\right)\)
\(n_{H_2SO_4\left(2\right)}=\dfrac{3}{2}n_{Al}=0,15\left(mol\right)\)
=> \(m_{ddH_2SO_4}=\dfrac{0,35.98}{20\%}=171,5\left(g\right)\)
d) \(m_{ddsaupu}=4,8+2,7+171,5-0,35.2=178,3\left(g\right)\)
\(C\%_{MgSO_4}=\dfrac{120.0,1}{178,3}.100=6,73\%\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,05}{178,3}.100=9,59\%\)
a,Mg+H2SO4-> MgSO4 +H2
2Al +3H2SO4 -> Al2(SO4)3 +3H2
b, n(Mg)=0,2mol
n(Al)=0,1mol
Số mol H2SO4=số mol H2= 0,2+ 0,1*3/2 =0,35mol
V(H2)= 7,84lit
c, MgSO4: m=0,2*120=24(g)
Al2(SO4)3 : m=342*0,05= 17,1(g)
d, khối lượng H2SO4= 0,35*98=34,3(g)
Khối lượng dd H2SO4 là:
m(dd)=34,3*100/20 = 171,5(g)
e,khối lượng dd sau pứ
m= m(Mg) +m(Al) + m(dd H2SO4) -m(H2) = 4,8+2,7+171,5-0,35*2=178,3(g)
C%(MgSO4)= 24*100%/178,3 =13,46%
C%(Al2SO4)3 = 17,1*100%/178,3 =9,59%
\(nMg=\dfrac{12}{24}=0,5\left(mol\right)\)
\(nH_2SO_4=\dfrac{29,4}{98}=0,3\left(mol\right)\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1 (mol)
0,3 0,3 0,3 0,3 (mol)
LTL : 0,5/1 > 0,3/1
=> Mg dư , H2SO4 đủ
\(VH_2=0,3.22,4=6,72\left(l\right)\)
m muối là mMgSO4
=> \(m\left(muối\right)=mMgSO_4=0,3.120=36\left(g\right)\)
a) PTHH: Fe + H2SO4 ===> FeSO4 + H2
b) Ta có: nFe =
Theo PTHH, nH2SO4 = nFe = 0,25 (mol)
=> mH2SO4 = 0,25 x 98 = 24,5 (gam)
c) Theo PTHH, nH2 = nFe = 0,25 (mol)
=> VH2(đktc) = 0,25 x 22,4 = 5,6 (l)
d) Theo PTHH, nFeSO4 = nFe = 0,25 (mol)
=> mFeSO4(tạo thành) = 0,25 x 152 = 38 (gam)
nMg = 3,6 : 24 = 0,15 (mol)
pthh : Mg + 2HCl --> MgCl2 + H2
0,15-----------> 0,15 --->0,15 (mol)
mMgCl2 = 0,15 . 95 = 14,25 (mol)
VH2 (đkc)= 0,15. 24,79 = 3,718(l)
\(n_{Mg}=\dfrac{3,6}{24}=0,15mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,15 0,3 0,15 0,15
\(m_{MgCl_2}=0,15\cdot95=14,25g\)
\(V_{H_2}=0,15\cdot22,4=3,36l\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Định Luật Bảo toàn khối lượng :
\(m_{Al}+m_{H_2SO_4}=m_{Al_2\left(SO_4\right)_3}+m_{H_2}\)
\(\Rightarrow m_{H_2}=2.7+14.7-17.1=0.3\left(g\right)\)
\(n_{H_2}=\dfrac{0.3}{2}=0.15\left(mol\right)\)
\(V_{H_2}=0.15\cdot22.4=3.36\left(l\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,1
\(m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2g\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right) \)
\(pthh:2Al+3H_2SO_{\text{ 4 }}->Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,1
=>\(m_{Al_2\left(SO_4\right)_4}=0,1.342=34,2\left(g\right)\)