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Ta có: \(\left\{{}\begin{matrix}n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,1.0,01=0,001\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=2.0,1.0,01=0,002\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\Sigma n_{H^+}=0,2.0,01+2.0,2.0,02=0,01\left(mol\right)\\n_{SO_4^{2-}}=n_{H_2SO_4}=0,2.0,02=0,004\left(mol\right)\end{matrix}\right.\)
PT ion: \(H^++OH^-\rightarrow H_2O\)
_____ 0,01___0,002_________ (mol)
⇒ H+ dư. \(\Rightarrow n_{H^+\left(dư\right)}=0,008\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\frac{0,008}{0,3}=\frac{2}{75}M\Rightarrow pH\approx1,57\)
PT ion: \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_{4\downarrow}\)
______ 0,001__0,004__ → 0,001 (mol)
\(\Rightarrow m_{\downarrow}=m_{BaSO_4}=0,001.233=0,233\left(g\right)\)
Bạn tham khảo nhé!
\(n_{NaOH}=0,1.0,01=0,001(mol)\\ \Rightarrow n_{OH^{-}}=0,001(mol)\\ n_{HCl}=0,03.0,2=0,006(mol)\\ \Rightarrow n_{H^{+}}=0,006(mol)\\ H^{+}+OH^{-}\to H_2O\\ 0,001<0,006\\ OH^{-} hêt; H^{+} dư\\ n_{H^{+}}=0,006-0,001=0,005(mol)\\ [H^{+}]=\frac{0,005}{0,1+0,2}=\frac{1}{60}M\\ \to pH=-log(\frac{1}{60})=1,77 \)
Bài 1:
Ta có: \(\Sigma n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,05.0,01+0,05.0,005.2=0,001\left(mol\right)\)
\(n_{H^+}=n_{HCl}=0,05.0,015=0,00075\left(mol\right)\)
PT ion: \(OH^-+H^+\rightarrow H_2O\)
______0,001__0,00075 (mol)
⇒ OH- dư. nOH- (dư) = 2,5.10-4 (mol)
\(\Rightarrow\left[OH^-\right]=\frac{2,5.10^{-4}}{0,1}=2,5.10^{-3}M\Rightarrow\left[H^+\right]=4.10^{-12}M\)
\(\Rightarrow pH\approx11,4\)
Bài 2: Đáp án D
Giải:
Ta có: \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1.0,002+0,2.2.x=2.10^{-4}+0,4x\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\frac{2.10^{-4}+0,4x}{0,3}M\)
\(\Rightarrow pH=-log\left(\frac{2.10^{-4}+0,4x}{0,3}\right)=2,7\)
\(\Rightarrow x\approx9,964.10^{-4}\approx10^{-3}\)
Bạn tham khảo nhé!
\(n_{H^+}=\left[H^+\right].V=10^{-1}.0,1=0,01\left(mol\right)\)
\(n_{OH^-}=0,1a\left(mol\right)\)
\(n_{OH^-\text{ dư}}=\left[OH^-\right].V=10^{-2}.\left(0,1+0,1\right)=0,002\left(mol\right)\)
Ta có:
\(n_{OH^-}-n_{OH^-\text{ dư}}=n_{H^+}\)
\(\Leftrightarrow0,1a-0,002=0,01\)
\(\Leftrightarrow a=0,12\)
\([H^{+}]=0,1M\\ \Rightarrow n_{H^{+}}=0,1.0,1=0,01(mol)\\ pH=12 \to pOH=14-12=2\\ \Rightarrow [OH^{-}]=0,01\\ \Rightarrow n_{OH^{-}}=0,002(mol)\\ H^{+} +OH^{-} \to H_2O\\ n_{NaOH}=0,01+0,002=0,012(mol)\\ \Rightarrow a=0,12M\)
n\(_{Ba\left(OH\right)_2}=0,1.0,5=0,05\left(mol\right)\)
\(Ba\left(OH\right)_2\rightarrow Ba^{2+}+2OH^-\)
0,05 0,05 0,1 (mol)
\(n_{KOH}=0,1.0,5=0,05\left(mol\right)\)
\(KOH\rightarrow K^++OH^-\)
0,05 0,05 0,05 (mol)
\(\left[H^+\right]=0,1-0,05=0,05\left(mol\right)\)
\(C_MH^+=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(\rightarrow PH=0,6020599913\simeq0,6\)
