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a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
Theo PTHH :
$n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$\Rightarrow m_{Zn} = 0,2.65 = 13(gam)$
$\Rightarrow m_{ZnO} = m_{hh} - m_{Zn} = 8,8 - 13 = -4,2 < 0$(Sai đề)
a) \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
_____0,2<---0,4<----0,2<----0,2
=> mMg = 0,2.24 = 4,8 (g)
=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{4,8}{8,8}.100\%=54,55\%\\\%MgO=\dfrac{8,8-4,8}{8,8}.100\%=45,45\%\end{matrix}\right.\)
b) \(n_{MgO}=\dfrac{8,8-4,8}{40}=0,1\left(mol\right)\)
PTHH: MgO + 2HCl --> MgCl2 + H2O
______0,1--->0,2
=> nHCl = 0,2 + 0,4 = 0,6 (mol)
=> \(V_{ddHCl}=\dfrac{0,6}{4}=0,15\left(l\right)\)
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
\(Zn+2HCl\rightarrow Zn+H_2\)
\(ZnO+2HCl\rightarrow Zn+H_2O\)
Ta có : \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(\%m_{Zn}=\dfrac{6,5}{14.6}.100=44,52\%\)
=> % m ZnO = 55,48%
a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: x x
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)
b,
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,6
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,2 0,4
nHCl = 0,6+0,4 = 1 (mol)
\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)
Phần 2:
nH2 = 0,03 => nAl dư = 0,02
nNaOH = nAl dư + 2nAl2O3 => nAl2O3 = 0,08
Phần 1:
nAl dư = 0,02k; nAl2O3 = 0,08k; nFe = a
=> 0,02k.27 + 0,08k.102 + 56a = 9.39
nH2 = 0.02k.1,5 + a = 0,105
k = 0.5 và a = 0,09
Fe : O = a : (0,08k.3) => Fe3O4
m2 = 9,39 + 9,39/k =28,17g
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
$n_{Zn} = n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$m_{Zn} = 0,1.65 = 6,5(gam)$
$m_{ZnO} = 14,6 - 6,5 = 8,1(gam)$
c)
$n_{ZnO} = \dfrac{8,1}{81} = 0,1(mol)$
$n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,4(mol)$
$\Rightarrow V_{dd\ HCl} = \dfrac{0,4}{C_{M_{HCl}}}$