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a. PTHH: \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\downarrow\)
\(KCl+AgNO_3\rightarrow KNO_3+AgCl\downarrow\)
\(n_{AgCl}=\frac{2,87}{143,5}=0,02mol\)
Đặt \(\hept{\begin{cases}x\left(mol\right)=n_{NaCl}\\y\left(mol\right)=n_{KCl}\end{cases}}\)
\(\rightarrow58,5x+74,5y=13,3\left(1\right)\)
Mà lấy đi \(\frac{1}{10}\) dung dịch A được 0,02 mol kết tủa \(\rightarrow x+y=10n_{AgCl}=0,2\left(2\right)\)
Từ (1) và (2) \(\rightarrow x=y=0,1mol\)
\(\rightarrow m_{NaCl}=0,1.58,5=5,85g\)
\(\rightarrow m_{KCl}=0,1.74,5=7,45g\)
b. \(C\%_{NaCl}=\frac{5,85}{500}.100\%=1,17\%\)
\(C\%_{KCl}=\frac{7,45}{500}.100\%=1,49\%\)
\(a.Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ n_{NaCl}=n_{HCl}=2.n_{CO_2}=2.\dfrac{448:1000}{22,4}=0,04\left(mol\right)\\ C_{MddHCl}=\dfrac{0,04}{0,02}=2\left(M\right)\\ b.m_{NaCl}=58,5.0,04=2,34\left(g\right)\\ c.m_{Na_2CO_3}=106.0,02=2,12\left(g\right)\\ \%m_{Na_2CO_3}=\dfrac{2,12}{5}.100=42,4\%\\ \%m_{NaCl}=100\%-42,4\%=57,6\%\)
Bài 16 :
\(n_{CO2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Pt : \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O|\)
1 2 2 1 1
0,02 0,04 0,04 0,02
a) \(n_{HCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)
20ml = 0,02l
\(C_{M_{HCl}}=\dfrac{0,04}{0,02}=2\left(M\right)\)
b) \(n_{NaCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)
⇒ \(m_{NaCl}=0,04.58,5=2,34\left(g\right)\)
c) \(n_{Na2CO3}=\dfrac{0,04.1}{2}=0,02\left(mol\right)\)
⇒ \(m_{Na2CO3}=0,02.106=2,12\left(g\right)\)
\(m_{NaCl}=5-2,12=2,88\left(g\right)\)
0/0Na2CO3 = \(\dfrac{2,12.100}{5}=42,4\)0/0
0/0NaCl = \(\dfrac{2,88.100}{5}=57,6\)0/0
Chúc bạn học tốt
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
a,Fe + 2HCl → FeCl + H2 (1)
FeO + 2HCl → FeCl + H2O (2)
nH2 = 3,36/ 22,4 = 0,15 ( mol)
Theo (1) nH2 = nFe = 0,15 ( mol)
mFe = 0,15 x 56 = 8.4 (g)
m FeO = 12 - 8,4 = 3,6 (g)
a, \(n_{H_2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
\(FeO+2HCl->FeCl_2+H_2O\left(2\right)\)
theo (1) \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
=> \(m_{Fe}=0,15.56=8,4\left(g\right)\)
=> \(m_{FeO}=12-8,4=3,6\left(g\right)\)
ta thấy : nFe =nH2 = 0,15
=> mFe =0,15 x 56 = 8,4g
%Fe=8,4/12 x 100 = 70%
=>%FeO = 100 - 70 = 30%
b) BTKLra mdd tìm mct of HCl
c) tìm mdd sau pứ -mH2 nha bạn
a) \(C\%=\dfrac{m_{KCl}}{m_{ddKCl}}.100\%=\dfrac{10}{300}.100\%\approx3,3\%\)
b) Đổi: \(1500ml=1,5l\)
\(C_{MCuSO_4}=\dfrac{n}{V}=\dfrac{3}{1,5}=2M\)
a)
$n_{HCl} = \dfrac{250.14,6\%}{36,5} = 1(mol)$
$Na_2CO_3 + 2HCl \to 2NaCl + CO_2 + H_2O$
$n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,5(mol)$
$V_{CO_2} = 0,5.22,4 = 11,2(lít)$
b)
Sau phản ứng :
$m_{dd} = 55 + 250 -0,5.44 = 283(gam)$
$n_{Na_2CO_3} = n_{CO_2} = 0,5(mol) \Rightarrow m_{Na_2SO_4} = 55 - 0,5.106 = 2(gam)$
$n_{NaCl} =n_{HCl} = 1(mol)$
$C\%_{NaCl} = \dfrac{1.58,5}{283}.100\% = 20,67\%$
$C\%_{Na_2SO_4} = \dfrac{2}{283}.100\% = 0,71\%$
a) \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
\(n_{HCl}=\dfrac{250.14,6\%}{36,5}=1\left(mol\right)\)
\(TheoPT:n_{CO_2}=\dfrac{1}{2}n_{HCl}=0,5\left(mol\right)\)
=> \(V_{CO_2}=0,5.22,4=11,2\left(l\right)\)
b) \(C\%_{NaCl}=\dfrac{0,5.58,5}{55+250-0,5.44}.100=10,34\%\)
\(m_{Na_2SO_4}=55-0,5.106=2\left(g\right)\)
=> \(C\%_{Na_2SO_4}=\dfrac{2}{55+250-0,5.44}.100=0,7\%\)
\(n_{CuSO_4}=\dfrac{50}{250}=0.2\left(mol\right)\)
\(n_{FeSO_4}=\dfrac{27.8}{278}=0.1\left(mol\right)\)
\(C_{M_{CuSO_4}}=C_{M_{FeSO_4}}=\dfrac{0.1}{0.1964}=0.5\left(M\right)\)
\(m_{dd_A}=50+27.8+196.4=274.2\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.1\cdot160}{274.2}\cdot100\%=6.47\%\)
\(C\%_{FeSO_4}=\dfrac{0.1\cdot152}{274.2}\cdot100\%=5.54\%\)
\(n_{CuSO_4.5H_2O}=\dfrac{50}{250}=0,2\left(mol\right)\)
=> \(m_{CuSO_4}=0,2.160=32\left(g\right)\)
\(m_{H_2O}=0,2.5.18=18\left(g\right)\)
\(n_{FeSO_4.7H_2O}=\dfrac{27,8}{278}=0,1\left(mol\right)\)=> \(m_{FeSO_4}=0,1.152=15,2\left(g\right)\)
\(m_{H_2O}=0,1.7.18=12,6\left(g\right)\)
\(m_{dd}=196,4+50+27,8=274,2\left(g\right)\)
\(V_{dd}=\dfrac{196,4+18+12,6}{1000}=0,227\left(l\right)\)
=> \(CM_{CuSO_4}=\dfrac{0,2}{0,227}=0,72M\)
\(C\%_{CuSO_4}=\dfrac{32}{274,2}.100=11,67\%\)
\(CM_{FeSO_4}=\dfrac{0,1}{0,227}=0,44M\)
\(C\%_{CuSO_4}=\dfrac{15,2}{274,2}.100=5,54\%\)
\(a.NaCl+AgNO_3\rightarrow AgCl\downarrow+NaNO_3\\ a.........a..........a........a\left(mol\right)\\ KCl+AgNO_3\rightarrow KNO_3+AgCl\downarrow\\ b........b......b.......b\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}585a+745b=13,3\\143,5a+143,5b=2,87\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,01\\b=0,01\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}m_{NaCl\left(bđ\right)}=0,01.10.58,5=5,85\left(g\right)\\m_{KCl}=0,01.10.74,5=7,45\left(g\right)\end{matrix}\right.\\ C\%_{ddNaCl\left(bđ\right)}=\dfrac{5,85}{500}.100=1,17\%\\ C\%_{ddKCl\left(bđ\right)}=\dfrac{7,45}{500}.100=1,49\%\)
a)
$NaCl + AgNO_3 \to AgCl + NaNO_3$
$KCl + AgNO_3 \to AgCl + KNO_3$
1/10 dung dịch A phản ứng $AgNO_3$ tạo 2,87 gam kết tủa
Suy ra : dung dịch A phản ứng $AgNO_3$ tạo 28,7 gam kết tủa
Gọi $n_{NaCl} =a (mol) ; n_{KCl} = b(mol) \Rightarrow 58,5a + 74,5b = 13,3(1)$
$n_{AgCl} = a + b = \dfrac{28,7}{143,5} = 0,2(2)$
Từ (1)(2) suy ra a = b = 0,1
$m_{NaCl} = 0,1.58,5 = 5,85(gam)$
$m_{KCl} = 74,5.0,1 = 7,45(gam)$
b)
$C\%_{NaCl} = \dfrac{5,85}{500}.100\% = 1,17\%$
$C\%_{KCl} = \dfrac{7,45}{500}.100\% = 1,49\%$