Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
a, \(\left[Na^+\right]=0,1\)
\(\left[K^+\right]=0,1\)
\(\left[OH^-\right]=0,2\)
\(\left[SO_4^{2-}\right]=0,2\)
\(\left[H^+\right]=0,4\)
b, \(n_{H^+}=0,1.0,4=0,04\left(mol\right)\)
\(n_{OH^-}=0,1.0,2=0,02\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
\(\Rightarrow n_{H^+dư}=0,02\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\dfrac{0,02}{200}=10^{-4}\)
\(\Rightarrow pH=4\)
$n_{NaOH} = n_{KOH} = 0,1.0,1 = 0,01(mol)$
$n_{H_2SO_4} = 0,02(mol)$
OH- + H+ → H2O
Bđ : 0,01...0,04..................(mol)
Pư : 0,01...0,01...................(mol)
Sau pư : 0......0,03...................(mol)
$V_{dd} = 0,1 + 0,1 = 0,2(lít)$
Vậy :
$[K^+] = [Na^+] = \dfrac{0,01}{0,2} = 0,05M$
$[H^+] = \dfrac{0,03}{0,2} = 0,15M$
$[SO_4^{2-}] = \dfrac{0,02}{0,2} = 0,1M$
b)
$pH = -log(0,15) = 0,824$
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02........0.02\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)
\(a.\)
\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)
\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)
\(b.\)
\(pH=14+log\left(0.1\right)=13\)
\(c.\)
\(H^++OH^-\rightarrow H_2O\)
\(0.02.......0.02\)
\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)
a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)
b) Ta có: \(pH=14+log\left[OH^-\right]=13\)
c) PT ion: \(OH^-+H^+\rightarrow H_2O\)
Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)
1) Ta coi H2SO4 điện li mạnh hai nấc.
\(n_{H_2SO_4}=0,03\) mol; \(n_{HCl}=0,16\) mol
\(H_2SO_4\rightarrow2H^++SO_4^-\)
0,03 -----> 0,06 ---> 0,03
\(HCl\rightarrow H^++Cl^-\)
0,16 --> 0,16 --> 0,16
\(\Rightarrow n_{H^+}=2n_{H_2SO_4}+n_{HCl}=2.0,03+0,16=0,22\) mol
+ \(\left[H^+\right]=\dfrac{0,22}{1+4}=0,044\) mol/lít
\(\Rightarrow pH=-lg\left[H^+\right]=-lg0,044=1,36\)
+ \(\left[SO_4^-\right]=\dfrac{0,03}{1+4}=6.10^{-3}\) mol/lít
+ \(\left[Cl^-\right]=\dfrac{0,16}{1+4}=0,032\) mol/lít
2) + \(n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,12\) mol
\(\Rightarrow\left[OH^-\right]=\dfrac{0,12}{5}=0,024\) mol/lít
\(\Rightarrow pOH=-lg\left[OH^-\right]=1,62\)
\(\Rightarrow pH=14-pOH=12,38\)
+ \(n_{Na^+}=n_{NaOH}=0,06\) mol
\(\Rightarrow\left[Na^+\right]=\dfrac{0,06}{5}=0,012\) mol/lít
+ \(n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,03\) mol
\(\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,03}{5}=0,006\) mol/lít
\(pH=2\Rightarrow\left[H^+_{dư}\right]=10^{-2}\Rightarrow n_{H^+}=10^{-2}\left(V+0,4\right)\)
\(n_{H^+}=2.0,0375.0,4+0,0125.0,4=0,035\left(mol\right)\)
\(n_{OH^-}=0,3V\left(mol\right)\)
\(\Rightarrow0,035+0,3V=10^{-2}\left(V+0,4\right)\)
\(\Rightarrow V=33,1\left(l\right)\)
\(\Leftrightarrow V=\)
\(n_{H^+}=0,1.2.0,2=0,04\Rightarrow\left[H^+\right]=\dfrac{0,04}{0,2+0,1}\approx0,13M\)
\(n_{SO_4^{2-}}=0,2.0,1+0,3.0,1=0,05\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,05}{0,2+0,1}\approx0,17M\)
\(n_{Na^+}=0,3.0,1.2=0,06\Rightarrow\left[Na^+\right]=\dfrac{0,06}{0,2+0,1}\approx0,2M\)
\(n_{HCl}=Cm.V=1.0,1=1mol\)
\(n_{H_2SO_4}=Cm.V=0,5.0,1=0,05mol\)
Thể thích của dd D là 200ml = 0,2l
\([H^+]=\frac{n_{HCl}+2.n_{H_2SO_4}}{V}=\frac{0,1+0,1}{0,2}=1M\)
\([Cl^-]=\frac{n_{HCl}}{V}=\frac{0,1}{0,2}=0,5M\)
\([SO_4^{2-}]=\frac{n_{H_2SO_4}}{V}=\frac{0,05}{0,2}=0,25M\)
Khi cho dd D vào \(Ba\left(OH\right)_2\) chỉ có \(H_2SO_4\) tác dụng, tạo kết tủa
\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)
\(0,05....\rightarrow0,05mol\)
\(\rightarrow m_{BaSO_4}=n.M=0,05.233=11,65g\)
\(n_{HCl}=0,1.0,1=0,01\left(mol\right);n_{HCl}=0,3.0,04=0,012\left(mol\right)\)
Dung dịch gồm H+ và Cl-
\(n_{H^+}=0,01+0,012=0,022\left(mol\right)\)
=> \(\left[H^+\right]=\dfrac{0,022}{0,4}=0,055M\)
\(n_{Cl^-}=0,01+0,012=0,022\left(mol\right)\)
=>\(\left[Cl^-\right]=\dfrac{0,022}{0,4}=0,055M\)
Trộn 100ml dung dịch HNO3 0.1M với 400ml dung dịch H2SO4 0.03M
\(n_{HNO_3}=0,1.0,1=0,01\left(mol\right);n_{H_2SO_4}=0,04.0,3=0,012\left(mol\right)\)
Dung dịch sau khi trộn gồm :
\(n_{H^+}=0,01+0,012.2=0,034\left(mol\right)\)
=> \(\left[H^+\right]=\dfrac{0,034}{0,5}=0,068M\)
\(n_{NO_3^-}=0,01\left(mol\right)\)
=>\(\left[NO_3^-\right]=\dfrac{0,01}{0,5}=0,02M\)
\(n_{SO_4^{2-}}=0,012\left(mol\right)\)
=> \(\left[SO_4^{2-}\right]=\dfrac{0,012}{0,5}=0,024M\)