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a. \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
a 2a a
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
b 3b 2b
b. \(n_{O_2}=\dfrac{25.88}{22.4}=1.155mol\)
n hỗn hợp khí \(=\dfrac{11.2}{22.4}=0.5mol\)
Ta có: \(\left\{{}\begin{matrix}a+b=0.5\\2a+3b=1.155\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.345\\b=0.155\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0.345\times22.4\times100}{11.2}=69\%\)
\(\%V_{C_2H_4}=100-69=31\%\)
c. \(V_{CO_2}=\left(a+2b\right)\times22.4=\left(0.345+2\times0.155\right)\times22.4=14.672l\)
a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
CH4+2O2-to>CO2+2H2O
x------2x---------x
C2H4+3O2-to>2CO2+2H2O
y----------3y--------2y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{5,6}{22,4}\\2x+3y=\dfrac{13,44}{22,4}\end{matrix}\right.\)
=>x=0,15 mol , y=0,1 mol
=>%VCH4=\(\dfrac{0,15.22,4}{5,6}\).100=60%
=>%VC2H4=100-60=40%
b)
VCO2=(0,15+0,1.2).22,4=7,84l
mhh khí = 5,6/22,4 = 0,25 (mol)
nO2 = 13,44/22,4 = 0,6 (mol)
Gọi nC2H4 = a (mol); nCH4 = b (mol)
a + b = 0,25 (1)
PTHH:
C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: a ---> 3a ---> 2a
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: b ---> 2b ---> b
3a + 2b = 0,6 (2)
(1)(2) => a = 0,1 (mol); b = 0,15 (mol)
%VC2H4 = 0,1/0,25 = 40%
%VCH4 = 100% - 40% = 60%
VCO2 = (0,1 . 2 + 0,15) . 22,4 = 7,84 (l)
\(a)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ 2C_2H_2 + 5O_2 \xrightarrow{t^o} 4CO_2 + 2H_2O\\ b)\\ V_{CH_4} =a (lít) ; V_{C_2H_2} = b(lít)\\ \Rightarrow a + b = 7,84(1)\\ V_{O_2} = 2a + \dfrac{5}{2}b = 21,28(2)\\ (1)(2) \Rightarrow a = -3,36 < 0 ; b = 11,2\)
(Sai đề)
\(n_{hhk}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{26,88}{22,4}=1,2\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\) ( mol ) \(\Rightarrow n_{hhk}=x+y=0,5\left(1\right)\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x 2x ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
y 3y ( mol )
\(\rightarrow n_{O_2}=2x+3y=1,2\left(2\right)\)
\(\left(1\right);\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0,3}{0,5}.100=60\%\)
\(\%V_{C_2H_4}=100-60=40\%\)