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$a\big)$
$n_{Fe}=\frac{16,8}{56}=0,3(mol)$
$3Fe+2O_2\xrightarrow{t^o}Fe_3O_4$
Theo PT: $n_{Fe_3O_4}=\frac{1}{3}n_{Fe}=0,1(mol)$
$\to m_{Fe_3O_4}=0,1.232=23,2(g)$
$b\big)$
Theo PT: $n_{O_2}=\frac{2}{3}n_{Fe}=0,2(mol)$
$\to V_{O_2}=0,2.22,4=4,48(l)$
$\to V_{kk}=4,48.5=22,4(l)$
$c\big)$
$2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2$
Theo PT: $n_{KMnO_4}=2n_{O_2}=0,4(mol)$
$\to m_{KMnO_4(dùng)}=\frac{0,4.158}{80\%}=79(g)$
a, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,3 0,2 0,1
\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
b, \(V_{O_2}=0,2.22,4=4,48\left(l\right)\Rightarrow V_{kk}=4,48.5=22,4\left(l\right)\)
c,
PTHH: 2KMnO4 ---to→ K2MnO4 + MnO2 + O2
Mol: 0,4 0,2
\(m_{KMnO_4\left(lt\right)}=0,4.158=63,2\left(g\right)\)
\(\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{63,2}{80\%}=79\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(n_{O_2}=\dfrac{0.896}{22.4}=0.04\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.06......0.04.......0.02\)
\(m_{Fe}=0.06\cdot56=3.36\left(g\right)\)
\(m_{Fe_2O_3}=0.02\cdot232=4.64\left(g\right)\)
\(n_{Fe}=\dfrac{33,6}{56}=0,6mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,6 0,4 0,2 ( mol )
\(V_{kk}=0,4.22,4.5=44,8l\)
\(m_{Fe_3O_4}=0,2.232=46,4g\)
\(n_{Fe}=\dfrac{1,68}{56}=0,03\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,03 0,02 0,01 ( mol )
\(m_{Fe_3O_4}=0,01.232=2,32\left(g\right)\)
\(V_{kk}=0,02.22,4.5=2,24\left(l\right)\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
\(\dfrac{1}{75}\) 0,02 ( mol )
\(m_{KClO_3}=\dfrac{1}{75}.122,5=1,63\left(g\right)\)
a,nFe=1,68/56=0,03 mol
Ta có PTHH : 3Fe + 2O2 --> Fe3O4 (1) ( ở trên dấu --> có to nha )
Theo PTHH ta có :
nFe3O4=1/3nFe=1/3.0,03=0,01 mol
nO2=2/3nFe=2/3.0,03=0,02 mol
=>mFe3O4= 0,01.232=2,32g
=>Vkk=5.(0,02.22,4)=2,24 l
b, Ta có PTHH: 2KClO3 --> 2KCl + 3O2 (2) ( trên dấu --> vẫn có to )
Gọi x là số mol KClO3 cần dùng ( x > 0 )
Theo PTHH (3) và theo bài ra ta có PTHH sau:
2/3x=0,02
=> x=0,03 mol
=> mKClO3= 0,03.122,5= 3,675g
gọi số mol Fe là x
pthh : 3Fe + 2O2 --t---> Fe3O4
x---->\(\dfrac{2}{3}\)x----------> \(\dfrac{x}{3}\)
=> mFe3O4= \(\dfrac{x}{3}\) . 232 = \(\dfrac{232x}{3}\) (G)
=> VO2 = \(\dfrac{2x}{3}\) . 22,4 = \(\dfrac{224x}{15}\) (L)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
nFe = 5,04 / 56 = 0,09 ( mol)
3Fe + 2O2 --(t^o)-- > Fe3O4
0,09 0,06 0,03 (mol)
=> mFe3O4 = 0,03 . 232 = 6,9(g)
=> VO2 = 0,06 . 22,4 = 1,344 (l)
=> Vkk = 1,344 . 5 = 6,72(l)