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a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
a, PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
b, \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,0175\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,0175.22,4}{0,86}.100\%\approx45,58\%\)
\(\Rightarrow\%V_{CH_4}\approx54,42\%\)
\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,5 0,5
\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)
\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)
\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)
\(\%V_{C_2H_4}=100\%-60\%=40\%\)
a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, - Khí thoát ra là CH4.
⇒ VCH4 = 4,48 (l)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{4,48}{11,2}.100\%=40\%\\\%V_{C_2H_4}=100-40=60\%\end{matrix}\right.\)
C2H4 + Br2 -> C2H4Br2
a a a
C2H2 + 2Br2 -> C2H2Br4
b 2b b
n hỗn hợp khí = \(\dfrac{7.84}{22.4}=0.35mol\)
Ta có: \(\left\{{}\begin{matrix}a+b=0.35\\160a+320b=72\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.25mol\\b=0.1mol\end{matrix}\right.\)
\(\%VC2H4=\dfrac{0.25\times22.4\times100}{7.84}=71.43\%\)
%VC2H2 = 100 - 71.43 = 28.57%
C2H4 + Br2 -> C2H4Br2
a a a
C2H2 + 2Br2 -> C2H2Br4
b 2b b
n hỗn hợp khí = 7.8422.4=0.35mol7.8422.4=0.35mol
Ta có: {a+b=0.35160a+320b=72⇔{a=0.25molb=0.1mol{a+b=0.35160a+320b=72⇔{a=0.25molb=0.1mol
%VC2H4=0.25×22.4×1007.84=71.43%%VC2H4=0.25×22.4×1007.84=71.43%
%VC2H2 = 100 - 71.43 = 28.57%
Gọi số mol của C2H4 và C2H2 lần lượt là x và y mol
theo bài ra: x+y = 0,56/22,4 = 0,025 (mol)
Pt:
C2H4 + Br2 → C2H4Br2
x mol x mol x mol
C2H2 + 2 Br2 → C2H2Br4
y mol 2y mol y mol
Số mol n Br2 = x+2y = 5,6/160 = 0,035 9mol)
Giải hệ ta đc: x = 0,015 và y = 0,01
=> %V C2H4 = 0,015/0,025 = 60% ; %V C2H2 = 40%
Bài 14 :
Vì metan không tác dụng với Brom nên :
\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)
a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_{2|}\)
1 1 1
0,025 0,025
b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)
\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)
\(V_{CH4\left(dktc\right)}=1,4-0,56=0,84\left(l\right)\)
0/0VCH4 = \(\dfrac{0,84.100}{1,4}=60\)0/0
0/0VC2H4 = \(\dfrac{0,56.100}{1,4}=40\)0/0
Chúc bạn học tốt
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b) Ta có: \(n_{Br_2}=\dfrac{11,2}{160}=0,07\left(mol\right)=n_{C_2H_4}\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,07\cdot22,4}{1,72}\cdot100\%\approx91,16\%\)
\(\Rightarrow\%V_{CH_4}=8,84\%\)