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1.1. Al + NaOH + H2O ==> NaAlO2 + 3/2H2
nH2(1)=3,36/22,4=0.15(mol)
=> nAl(1)= nH2(1):3/2= 0.15:3/2= 0.1(mol)
2.Mg + 2HCl ==> MgCl2 + H2
3.2Al + 6HCl ==> 2AlCl3 + 3H2
4.Fe + 2HCl ==> FeCl2 + H2
=> \(n_{H_2\left(2,3,4\right)}=\) 10.08/22.4= 0.45(mol)
=> nH2(3)=0.1*3/2=0.15(mol)
MgCl2 + 2NaOH ==> Mg(OH)2 + 2NaCl
AlCl3 + 3NaOH ==> Al(OH)3 + 3NaCl
FeCl2 + 2NaOH ==> Fe(OH)2 + 2NaCl
a, Giả sử: \(\left\{{}\begin{matrix}n_{CO_2}=x\left(mol\right)\\n_{SO_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{0,224}{22,4}=0,01\left(1\right)\)
Mà: \(\overline{M}_A=56\Rightarrow44x+64y=56.0,01\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,004\left(mol\right)\\y=0,006\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%n_{CO_2}=\dfrac{0,004}{0,01}.100\%=40\%\\\%n_{SO_2}=60\%\end{matrix}\right.\)
BTNT C và S, có: \(\left\{{}\begin{matrix}n_{Na_2CO_3}=n_{CO_2}=0,004\left(mol\right)\\n_{Na_2SO_3}=n_{SO_2}=0,006\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na_2CO_3}=\dfrac{0,004.106}{0,004.106+0,006.126}.100\%\approx35,9\%\\\%m_{Na_2SO_3}\approx64,1\%\end{matrix}\right.\)
b, Ta có: \(n_{HCl}=0,05.0,2=0,01\left(mol\right)\)
PT: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
____0,005_______0,01 (mol)
\(Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3+H_2O\)
_0,004______0,004 (mol)
\(Ba\left(OH\right)_2+SO_2\rightarrow BaSO_3+H_2O\)
_0,006_____0,006 (mol)
\(\Rightarrow n_{Ba\left(OH\right)_2}=0,015\left(mol\right)\)
\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,015}{1}=0,015M\)
Bạn tham khảo nhé!
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=0,1(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,1.24}{6,4}.100\%=37,5\%\\ \Rightarrow \%_{MgO}=100\%-37,5\%=62,5\%\)
\(b,n_{MgO}=\dfrac{6,4-0,1.24}{40}=0,1(mol)\\ \Rightarrow n_{HCl}=2.0,1+2.0,1=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(l)\\ c,n_{MgCl_2}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{MgCl_2}}=\dfrac{0,2}{0,8}=0,25M\)
