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\(n_{HCl}=0,2.3,5=0,7\left(mol\right)\\ n_{CuO}=a;n_{Fe_2O_3}=b\\ CuO+2HCl\xrightarrow[]{}\Rightarrow CuCl_2+H_2O\\ Fe_2O_3+6HCl\xrightarrow[]{}2FeCl_3+H_2O\\ \left\{{}\begin{matrix}2a+6b=0,7\\80a+160b=20\end{matrix}\right.\\\Rightarrow a=0,05;b=0,1\\ \%_{CuO}=\dfrac{0,05.80}{20}\cdot100=20\%\\ \%_{Fe_2O_3}=\dfrac{0,1.160}{20}\cdot100=80\%\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
nNaOH=0.01(mol)
2NaOH+SO2->Na2SO3+H2O
0.01 0.005
V=0.112(l)
2)nHCl=0.5(mol)
MgO+2HCl->MgCl2+H2O
x 2x
Fe2O3+6HCl->2FeCl3+3H2O
y 6y
Theo bài ra:40x+160y=12
2x+6y=0.5
x=0.1(mol) mMgO=4(g)
y=0.05(mol) mFe2O3=8(g)
Gọi x,y lần lượt là số mol Al2O3, CuO
Al2O3 + 3H2SO4 → Al2(SO4)3 + 3H2O
CuO + H2SO4 → H2O + CuSO4
\(\left\{{}\begin{matrix}102x+80y=12,3\\3x+y=\dfrac{100.24,5\%}{98}=0,25\end{matrix}\right.\)
=> x= 0,056; y=0,082
=> \(\%m_{Al_2O_3}=\dfrac{0,056.102}{12,3}.100=46,44\%\)
=> %mCuO= 100 - 46,44= 53,56%
b)
Al2O3 + 6HCl → 2AlCl3 + 3H2O
CuO + 2HCl → CuCl2 + H2O
=> \(m_{HCl}=\dfrac{(0,056.6+0,082.2).36,5}{7\%}=260,7\%\)
\(n_{HCl}=1.0,2=0,2(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ \Rightarrow n_{Mg}=\dfrac{1}{2}n_{HCl}=0,1(mol)\\ \Rightarrow m_{Mg}=0,1.24=2,4(g)\\ \Rightarrow m_{Cu}=10-2,4=7,6(g)\)
Đặt: nMgO=x(mol) ; nCuO=y(mol) (x,y>0)
nHCl=0,2.2=0,4(mol)
PTHH: MgO +2 HCl -> MgCl2 + H2
x________2x__________x___x(mol)
CuO +2 HCl -> CuCl2 + H2
y___2y______y_____y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}40x+80y=10\\2x+2y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,05\end{matrix}\right.\)
=> mMgO= 0,15.40=6(g); mCuO= 0,05.80=4(g)
Cảm ơn bạn nha