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a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{2}n_{O_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Có: O2 hao hụt 40% → H% = 100 - 40 = 60%
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,4\left(mol\right)\)
\(\Rightarrow n_{KMnO_4\left(TT\right)}=\dfrac{0,4}{60\%}=\dfrac{2}{3}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=\dfrac{2}{3}.158\approx105,3\left(g\right)\)
4Al+3O2-to>2Al2O3
0,04---0,03------0,02 mol
n Al=\(\dfrac{1,08}{27}\)=0,04 mol
=>VO2=0,03.22,4=0,672l
b)
2A+O2-to>2AO
0,06--0,03 mol
=>\(\dfrac{3,84}{A}=0,06\)
=>A=64 :=>Al là Đồng
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,2mol\\n_{Fe_3O_4}=0,1mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4}=0,1\cdot232=23,2\left(g\right)\\V_{O_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bạn tách ra từng câu nhé!
Bài 3.
\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{36}{56}=0,6428mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,6428 ----- 0,4285 ( mol )
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,857 0,4285 ( mol )
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=0,857.158=135,406g\)
Bài 4.
a.\(n_{Al_2O_3}=\dfrac{m_{Al_2O_3}}{M_{Al_2O_3}}=\dfrac{51}{102}=0,5mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
1 0,75 0,5 ( mol )
\(m_{Al}=n_{Al}.M_{Al}=1.27=27g\)
\(V_{O_2}=n_{O_2}.22,4=0,75.22,4=16,8l\)
b.\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
1,5 0,75 ( mol )
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=1,5.158=237g\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
0,5 0,75 ( mol )
\(m_{KClO_3}=n_{KClO_3}.M_{KClO_3}=0,5.122,5=61,25g\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)