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\(a,\\ 1,\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ 2,\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow n_{Al}=\dfrac{0,6.2}{3}=0,4\left(mol\right)\\ n_{Zn}=n_{H_2}=0,6\left(mol\right)\\ m_{Al}=0,4.27=10,8\left(g\right)\\ m_{Zn}=65.0,6=39\left(g\right)\\ \Rightarrow m_{Al}< m_{Zn}\\ b,Đặt:n_{Al}=n_{Zn}=1\left(mol\right)\\ \Rightarrow n_{H_2\left(1\right)}=1,5.1=1,5\left(mol\right)\\ n_{H_2\left(2\right)}=n_{Zn}=1\left(mol\right)\\ Vì:1,5>1\)
=> Cùng lấy một khối lượng kim loại Al hoặc Zn cho phản ứng thì lượng H2 sinh ra từ phản ứng có Al sẽ nhiều hơn.
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right);n_{ZnCl_2}=\dfrac{27,2}{136}=0,2\left(mol\right)\)
PTHH(1): 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,2 0,3
PTHH(2): Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,2 0,2
Ta có: \(n_{H_2\left(1\right)}=0,5-0,2=0,3\left(mol\right)\)
\(m_{hh}=0,2.27+0,2.65=18,4\left(g\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ b.n_{Zn}=n_{ZnCl_2}=0,1\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,1\left(mol\right)\\ \Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
a) Zn + 2HCl → ZnCl2 + H2
b) mZnCl2 = 0,1 . 136 = 13,6 gam
c) nZn = 6,5/65 = 0,1 mol . Theo tỉ lệ pư => nH2 = nZn = nZnCl2 =0,1 mol <=> VH2(đktc) = 0,1.22,4 = 2,24 lít.
\(n_{Zn} = a(mol) ; n_{Al} = b(mol) ; n_{Mg} = c(mol)\\ \Rightarrow 65a + 27b + 24c = 44,1(1)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3 H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{31,36}{22,4} = 1,4(2)\\ Mà : 2a = 3b(3)\\ (1)(2)(3) \Rightarrow a = 0,3 ; b = 0,2 ; c = 0,8\\ \%m_{Zn} = \dfrac{0,3.65}{44,1}.100\% = 44,22\%\\ \%m_{Al} = \dfrac{0,2.27}{44,1}.100\% = 12,24\%\)
\(\%m_{Mg} = 100\% -44,22\% -12,24\% = 43,54\%\)
a) \(n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{3}{14}\)---------------------->\(\dfrac{3}{14}\)
\(\Rightarrow V_{H_2}=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
b) \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
PTHH: \(ZnO+H_2\xrightarrow[]{t^o}Zn+H_2O\)
Xét tỉ lệ: \(0,1< \dfrac{3}{14}\Rightarrow H_2\) dư
Theo PT: \(n_{Zn}=n_{ZnO}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(1mol\) \(1mol\)
\(\dfrac{3}{14}mol\) \(\dfrac{3}{14}mol\)
\(a)n_{Fe}=\dfrac{m}{M}=\dfrac{12}{56}\approx0,21=\dfrac{3}{14}\left(mol\right)\)
\(V_{H_2}=n.22,4=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
\(b)n_{ZnO}=\dfrac{m}{M}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(ZnO+H_2\rightarrow Zn+H_2O\)
\(1mol\) \(1mol\) \(1mol\)
\(0,1mol\) \(0,1mol\) \(0,1mol\)
\(\text{Ta thấy }H_2\text{ dư,ZnO phản ứng hết.Bài toán tính theo ZnO}\)
\(m_{Zn}=n.M=0,1.65=6,5\left(g\right)\)
a) PTHH: NaOH + Al + H2O -> NaAlO2 + 3/2 H2
b) nH2= 0,6(mol)
-> nAl=0,4(mol) => mAl=0,4.27=10,8(g)
c) nAl=0,18((mol); nNaOH=0,2(mol)
PTHH: 0,18/1 < 0,2/1
=> Al hết, NaOH dư, tính theo nAl.
-> nH2= 3/2. 0,18=0,27(mol)
=>V(H2,đktc)=0,27.22,4= 6,048(l)
\(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)
\(2NaOH+2Al+2H_2O\rightarrow2NaAlO_2+3H_2\)
\(...........0.4.........................0.6\)
\(m_{Al}=0.4\cdot27=10.8\left(g\right)\)
\(n_{Al}=\dfrac{4.86}{27}=0.18\left(mol\right)\)
\(n_{NaOH}=\dfrac{8}{40}=0.2\left(mol\right)\)
\(2NaOH+2Al+2H_2O\rightarrow2NaAlO_2+3H_2\)
\(2.................2\)
\(0.2...............0.18\)
\(LTL:\dfrac{0.2}{2}>\dfrac{0.18}{2}\)
\(\Rightarrow NaOHdư\)
\(n_{H_2}=0.18\cdot\dfrac{3}{2}=0.27\left(mol\right)\)
\(V_{H_2}=0.27\cdot22.4=6.048\left(l\right)\)
