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\(n_{CO_2\left(đktc\right)}=\dfrac{10,64}{22,4}=0,475\left(mol\right)\\a, K_2CO_3+2CH_3COOH\rightarrow2CH_3COOK+CO_2+H_2O\\ b,n_{K_2CO_3}=n_{CO_2}=0,475\left(mol\right)\\ \Rightarrow m_{K_2CO_3}=138.0,475=65,55\left(g\right)\\ n_{CH_3COOH}=0,475.2=0,95\left(mol\right)\\ C\%_{ddCH_3COOH}=\dfrac{0,95.60}{200}.100=28,5\%\)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,4--->0,8------>0,4--->0,4
=> VH2 = 0,4.22,4 = 8,96(l)
c) mHCl = 0,8.36,5 = 29,2 (g)
=> \(m_{dd\left(HCl\right)}=\dfrac{29,2.100}{7,3}=400\left(g\right)\)
mdd (sau pư) = 22,4 + 400 - 0,4.2 = 421,6 (g)
=> \(C\%\left(FeCl_2\right)=\dfrac{127.0,4}{421,6}.100\%=12,05\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)
Na2O+H2O->2NaOH
0,2----------------0,4 mol
2NaOH+CO2->Na2CO3+H2O
0,4--------0,2
n Na2O=12,4\62=0,2 mol
=>C% NaOH=0,4.40\12,4+120 .100=3 %
=>m CO2=0,2.44=8,8g
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Fe}=0,2.174=34,8\left(g\right)\)
Ta có: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\)
m dd sau pư = 11,2 + 200 - 0,2.2 = 210,8 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{34,8}{210,8}.100\%\approx16,51\%\)
Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
\(n_{CH_3COOH}=\dfrac{130.12}{100.60}=0,26\left(mol\right)\)
\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
0,13 0,26 0,13 0,13 ( mol )
\(m_{CaCO_3}=0,13.100=13\left(g\right)\)
\(V_{CO_2}=0,13.22,4=2,912\left(l\right)\)
\(m_{ddspứ}=13+130-0,13.44=137,28\left(g\right)\)
\(C\%_{\left(CH_3COO\right)_3Ca}=\dfrac{0,13.158}{137,28}.100=14,96\%\)