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\(\begin{array} {l} 13)\\ n_{HCHO}=\dfrac{1,2}{30}=0,04(mol)\\ HCHO\xrightarrow{+AgNO_3/NH_3,t^o}4Ag\\ n_{Ag}=4n_{HCHO}=0,16(mol)\\ m=0,16.108=17,28(g)\\ \to A\\ 14)\\ X:C_nH_{2n}\\ n_{Br_2}=\dfrac{8}{160}=0,05(mol)\\ C_nH_{2n}+Br_2\to C_nH_{2n}Br_2\\ n_{C_nH_{2n}}=n_{Br_2}=0,05(mol)\\ M_{C_nH_{2n}}=14n=\dfrac{1,4}{0,05}=28(g/mol)\\ n=2\\ X:C_2H_4\\ \to A \end{array}\)
\(m_{H_2O}=1,62\left(g\right)\Rightarrow n_{H_2O}=0,09\left(mol\right)\Rightarrow n_H=0,18\left(mol\right);m_H=0,18.1=0,18\left(g\right)\\ n_{CO_2}=\dfrac{2,64}{44}=0,06\left(mol\right)\Rightarrow n_C=n_{CO_2}=0,06\left(mol\right);m_C=0,06.12=0,72\left(g\right)\\ Vây:m_C+m_H=0,72+0,18=0,9< 1,38\\ \Rightarrow X.có.chứa.O\\ m_O=1,38-0,9=0,48\left(g\right);n_O=\dfrac{0,48}{16}=0,03\left(mol\right)\\ Đặt.X:C_aH_bO_c\left(a,b,c:nguyên,dương\right)\\ Ta.có:a:b:c=0,06:0,18:0,03=2:6:1\\ \Rightarrow CTĐG:C_2H_6O\\ M_X=23.2=46\left(\dfrac{g}{mol}\right)=M_{C_2H_6O}\\ \Rightarrow X:C_2H_6O\)
Ta có: AA'\(\perp\)(ABCD) (giả thiết).
Suy ra, (ABCD)\(\perp\)(ACC'A').
Vậy góc tạo bởi hai mặt phẳng đã cho là 90o.
Chọn D.
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\\ C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{C_2H_4}=n_{Br_2}=0,05\left(mol\right)\\ \Rightarrow V_{C_2H_4\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ \%V_{\dfrac{C_2H_4}{hh}}=\dfrac{1,12}{3,36}.100\approx33,33\%\\ \Rightarrow\%V_{\dfrac{CH_4}{hh}}=\dfrac{3,36-1,12}{3,36}.100\approx66,67\%\)
a)
P1:
\(n_{Br_2}=\dfrac{80.20\%}{160}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<--0,1
=> \(n_{C_2H_4\left(P_1\right)}=0,1\left(mol\right)\)
=> \(m_{C_3H_8\left(P_1\right)}=\dfrac{12,2}{2}-0,1.28=3,3\left(g\right)\)
=> \(n_{C_3H_8\left(P_1\right)}=\dfrac{3,3}{44}=0,075\left(mol\right)\)
=> \(V=\left(0,1.2+0,075,2\right).22,4=7,84\left(l\right)\)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1}{0,1+0,075}.100\%=57,143\%\\\%V_{C_3H_8}=\dfrac{0,075}{0,1+0,075}.100\%=42,857\%\end{matrix}\right.\)
b) P2 \(\left\{{}\begin{matrix}C_2H_4:0,1\left(mol\right)\\C_3H_8:0,075\left(mol\right)\end{matrix}\right.\)
Bảo toàn C: \(n_{CO_2}=0,425\left(mol\right)\) => \(n_{BaCO_3}=0,425\left(mol\right)\)
Bảo toàn H: \(n_{H_2O}=0,5\left(mol\right)\)
Xét \(\Delta m=m_{CO_2}+m_{H_2O}-m_{BaCO_3}=0,425.44+0,5.18-0,425.197=-56,025\left(g\right)\)
=> khối lượng dd sau pư giảm 56,025 gam