Cho 12 gam Magie tác dụng vừa đủ với dung dịch H2SO4 loãng.
a, Tính thể tích H2 thu được ở đktc?
b, Cho khí H2 thu được ở trên đi qua bình đựng CuO nung nóng. Tính khối lượng Cu thu được?
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{Al}=\dfrac{16,2}{27}=0,6\left(mol\right)\)
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
0,6 0,9 0,3 0,9
\(\rightarrow V_{H_2}=0,9.22,4=20,16\left(l\right)\)
\(n_{Cu}=\dfrac{57}{64}=0,890625\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,890625 0,890625
\(H=\dfrac{0,890625}{0,9}=99\%\)
\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.2.......0.4........................0.2\)
\(C_{M_{HCl}}=\dfrac{0.4}{0.2}=2\left(M\right)\)
\(n_{CuO}=\dfrac{32}{80}=0.4\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
Lập tỉ lệ : \(\dfrac{0.4}{1}>\dfrac{0.2}{1}\)
=> CuO dư
\(m_{cr}=m_{CuO\left(dư\right)}+m_{Cu}=32-0.2\cdot80+0.2\cdot64=28.8\left(g\right)\)
\(\%Cu=\dfrac{0.2\cdot64}{28.8}\cdot100\%=44.44\%\)
\(\%CuO\left(dư\right)=55.56\%\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
0,1 0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: \(0,4>0,15\rightarrow\) CuO dư
Theo pthh: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,15.64}{0,15.64+\left(0,4-0,15\right).80}=32,43\%\\\%m_{CuO}=100\%-32,43\%=67,57\%\end{matrix}\right.\)
a. \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\)
b. \(n_{Al}=\frac{m}{M}=\frac{2,7}{27}=0,1mol\)
Theo phương trình `(1)` \(n_{H_2}=\frac{3}{2}.n_{Al}=\frac{3}{2}.0,1=0,15mol\)
\(\rightarrow V_{H_2\left(ĐKTC\right)}=n.22,4=0,15.22,4=3,36l\)
c. \(CuO+H_2\rightarrow^{t^o}Cu+H_2O\left(2\right)\)
\(n_{CuO}=\frac{m}{M}=\frac{32}{80}=0,4mol\)
Tỷ lệ \(\frac{0,4}{1}>\frac{0,15}{1}\)
`->CuO` dư
Theo phương trình `(2)` \(n_{Cu}=n_{H_2}=0,15mol\)
\(n_{CuO\left(pứ\right)}=n_{H_2}=0,15mol\)
\(\rightarrow n_{CuO\left(dư\right)}=0,4-0,15=0,25mol\)
\(m\left(g\right)\text{ chất rắn }\hept{\begin{cases}CuO_{dư}=0,25mol\\Cu=0,15mol\end{cases}}\)
\(\rightarrow m=0,15.64+0,25.80=29,6g\)
\(\%m_{CuO\left(dư\right)}=\frac{0,25.80.100}{29,6}\approx67,6\%\)
\(\%m_{Cu}=100\%-67,6\%=32,4\%\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,05 0,1 0,05 0,05
a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\)
b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.
Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
a.b.\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,15 ( mol )
\(V_{H_2}=n_{H_2}.22,4=0,15.22,4=3,36l\)
c.\(n_{CuO}=\dfrac{m_{CuO}}{M_{CuO}}=\dfrac{16}{80}=0,2mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,2 < 0,15 ( mol )
0,15 0,15 0,15 ( mol )
\(m_A=m_{CuO\left(dư\right)}+m_{Cu}=\left[\left(0,2-0,15\right).80\right]+\left[0,15.64\right]=4+9,6=13,6g\)
a.b.\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{5,4}{27}=0,2mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 ( mol )
\(V_{H_2}=n_{H_2}.22,4=0,3.22,4=6,72l\)
c.\(n_{CuO}=\dfrac{m_{CuO}}{M_{CuO}}=\dfrac{32}{80}=0,4mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,4 < 0,3 ( mol )
0,3 0,3 0,3 ( mol )
\(m_A=m_{CuO\left(du\right)}+m_{Cu}=\left[\left(0,4-0,3\right).80\right]+\left(0,3.64\right)=8+19,2=27,2g\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2---------------------->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b)
\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,3<--0,3------->0,3
=> Rắn sau pư gồm \(\left\{{}\begin{matrix}Cu:0,3\left(mol\right)\\CuO\left(dư\right):0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,3.64}{0,3.64+0,1.80}.100\%=70,59\%\\\%m_{CuO}=\dfrac{0,1.80}{0,3.64+0,1.80}.100\%=29,41\%\end{matrix}\right.\)
a. \(n_{Zn}=\dfrac{2,6}{65}=0,04\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
- Mol theo PTHH : \(1:1:1:1\)
- Mol theo phản ứng : \(0,04\rightarrow0,04\rightarrow0,04\rightarrow0,04\)
\(\Rightarrow m_{ZnSO_4}=n_{ZnSO_4}.M_{ZnSO_4}=0,04.161=6,44\left(g\right)\)
b. Từ a. suy ra : \(V_{H_2}=n_{H_2}.22,4=0,04.22,4=0,896\left(l\right)\)
c. Từ a. suy ra : \(n_{H_2}=0,04\left(mol\right)\)
\(PTHH:H_2+PbO\underrightarrow{t^o}Pb+H_2O\)
- Mol theo PTHH : \(1:1:1:1\)
- Mol theo phản ứng : \(0,04\rightarrow0,04\rightarrow0,04\rightarrow0,04\)
\(\Rightarrow m_{Pb}=n_{Pb}.M_{Pb}=0,04.207=8,28\left(g\right)\)
a, PT: \(Mg+H_2SO_{4\left(l\right)}\rightarrow MgSO_4+H_2\)
Ta có: \(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
b, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Theo PT: \(n_{Cu}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,5.64=32\left(g\right)\)
Bạn tham khảo nhé!