Một dung dịch chứa 0,5 mol axit clohidric
a) Tìm khối lượng axit clohidric
b) Cho 1 lượng bột kẽm vào axit trên. Tính thể tích khí hidro bay lên và khối lượng kẽm phản ứng
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a) Có: \(n_{HCl}=0,5mol\)
\(\Rightarrow m_{HCl}=0,5.\left(1+35,5\right)=18,25g\)
b)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Có: \(n_{HCl}=0,5mol\)
Theo PTHH:
\(\Rightarrow n_{H_2}=0,25mol\)
\(\Rightarrow V_{H_2}=0,25.22,4=5,6l\)
\(n_{Zn}=0,25mol\)
\(\Rightarrow m_{Zn}=0,25.65=16,25g\)
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1. Bảng hóa trị một số nguyên tố hóa học.
Số proton | Tên Nguyên tố | Nguyên tử khối |
---|---|---|
20 | Canxi | 40 |
24 | Crom | 52 |
25 | Mangan | 55 |
26 | Sắt | 56 |
a) \(n_{Zn}=\frac{m}{M}=\frac{13}{65}=0,2\left(mol\right)\)
Phương trình hóa học phản ứng
Zn + H2SO4 ---> ZnSO4 + H2
1 : 1 : 1 : 1
0.2 0,2 0,2
mol mol mol
=> \(V_{H_2}=n.22,4=0,2.22,4=4,48\left(l\right)\)
b) \(m_{ZnSO_4}=n.M=0,2.161=32,2\left(g\right)\)
c) Ta có \(C\%=\frac{m_{ct}}{m_{dd}}.100\%=24,5\%\)
=> \(m_{ct}=\frac{C\%.m_{dd}}{100\%}=\frac{24,5\%.200}{100\%}=49\left(g\right)=m_{H_2SO_4}\)
=> \(m_{H_2O}=151\left(g\right)\)
=> \(n_{H_2SO_4}=\frac{m}{M}=\frac{49}{98}=0,5\)(mol)
Dễ thấy \(\frac{n_{Zn}}{1}< \frac{n_{H_2SO_4}}{1}\)
=> H2SO4 dư 0,5 - 0,2 = 0,3 (mol)
=> \(m_{H_2SO_4\text{ dư }}=n.M=0,3.98=29,4\left(g\right)\); \(m_{H_2SO4\text{ tham gia}}=n.M=0,2.98=19,6\)(g)
Áp dụng đinhk luật bảo toàn khối lượng
=> \(m_{H_2SO_4}+m_{Zn}=m_{ZnSO4}+m_{H_2}\)
=> \(m_{H_2}=m_{H_2SO_4}+m_{Zn}-m_{ZnSO_4}=19,6+13-32,2=0,4\left(g\right)\)
=> \(m_{saupư}=m_{ZnSO_4}+m_{H_2SO_4\text{ dư}}+m_{H_2O}-m_{H_2}=32,2+29,4+151-0,4=232,2\left(g\right)\)
=> \(C\%_{H_2SO_4}=\frac{m_{ct}}{m_{sau\text{ pư}}}.100\%=\frac{29,4}{232,2}.100\%=12,66\%\)
\(C\%_{ZnSO_4}=\frac{m_{ct}}{m_{dd}}.100\%=\frac{32,2}{232,2}.100\%=13,87\%\)
\(nC_2H_4=\frac{3,36}{22,4}=0,15mol\)
\(C_2H_4+3O_2\rightarrow2CO_2+2H_2O\)
\(nO_2=3nC_2H_4=0,45mol\)
\(\rightarrow VO_2=0,45.24,79=11,1555l\)
a) m HCl \(0,5.\left(36,5\right)=18,25g\)
b) Zn +2HCl -> ZnCl2 +H2
0,25...0,5...................0,25
V H2 = 0,25.22,4 =5,6 lít
m Zn = 0,25.65=16,25g